Coloration behaviors of phthalocyanine reactive dye on nylon substrates: experiments, empirical modeling and statistical analysis

KIM BYUNG-SOON (김병순); K. Ravikumar; 윤석한; Young-A Son

Coloration behaviors of phthalocyanine reactive dye on nylon substrates: experiments, empirical modeling and statistical analysis

Textile Coloration and Finishing
Abbr : Text. Color. and Finish.
2007, 19(2), pp.14-23
Publisher : The Korean Society Of Dyers And Finishers
Research Area : Engineering > Fiber Engineering > Dyeing Engineering

KIM BYUNG-SOON ¹, K. Ravikumar ², 윤석한 ³, Young-A Son ²

¹충남대학교
²Chungnam National University
³Korea Dyeing Technology Center

Accredited

ABSTRACT

This research article explores the use of phthalocyanine reactive dye on nylon substrate. The effect of factors such as pH, temperature, liquor ratio and alkali addition on level of dye exhaustion, fixation and total fixation efficiency. Low pH, high temperature and low liquor ratio were found to be suitable conditions for maximum % exhaustion values. The effect of sulphatoethylsulphone (SES) and vinylsulphone (VS) form of the dyes on level of dye fixation was also discussed. The optimized exhaustion (%E), fixation (%F) and total fixation efficiency were determined. Modification of the dyeing process with alkali addition displayed that dye fixation (%) increased by alkali addition. Vinylsulphone (VS) moiety of the dye was found to be superior for maximum fixation (%F). Appropriate predictable empirical models, relatively a new approach in dyeing processes, were developed incorporating interactions effects of temperature, pH and liquor ratio for predicting % exhaustion, fixation and total fixation efficiency. The significance of the mathematical model developed was ascertained using microsoft excel regression (solver) analysis module. High correlation coefficient was obtained (R2=0.9895 for % exhaustion, R2=0.9932 for fixation, R2=0.9965 for total fixation efficiency) for the model which shows prominent prediction capacity of the model for any conditions. The predictable polynomial equations developed from the experimental results were thoroughly analyzed by ANOVA (Analysis of Variance) statistical concepts.

KEYWORDS

nylon substrate, phthalocyanine reactive dye, empirical modeling, statistical analysis1. IntroductionPhthalocyanines are well documented group of synthetic dyes that can be used as industrial dyes, optical sensors, in electrocatalytic oxidation etc.

Citation status

* References for papers published after 2023 are currently being built.

[journal] / 2007 / Optical absorption studies of copper phthalocyanine thin films 39 : 728~732

[journal] / 2006 / Dyeing of nylon with reactive dyes. Part 1. The effect of changes in dye structure on the dyeing of nylon with reactive dyes 68 : 109~117

[journal] / 2003 / Application of an Anionic Syntan on Nylon 6.6 Fibers: Exhaustion Properties and Staining Resistance 15 : 18~26

[journal] / 2001 / The aftertreatment of acid dyes on nylon 6,6 fibres Part 1. 1:2 pre-metallised acid dyes 48 : 57~69

[journal] / 2005 / A study of heterobifunctional reactive dyes on nylon fibers: dyeing propertied, dye moiety analysis and wash fastness 66 : 231~239

[journal] / 2002 / Removal of a copper-phthalocyanine dye from wastewater by acclimated sludge under anaerobic or aerobic conditions 37 : 1151~1156

[journal] / 1951. / Methods of correlation analysis / John Wiley & Sons Inc.

[journal] / 1975. / Applied Mathematics in Chemical Engineering / Tata McGraw-Hill

[journal] / 2001 / The application of heterobifunctional reactive dyes to nylon 6,6: process modifications to achieve high efficiencies 48 : 245~251

[journal] / 1991. / Design and Analysis of Experiments / John Wiley & Sons Inc.

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