@article{ART002015338},
author={Subhash Kumar and Manoj Srivastava},
title={Mesophase formation behavior in petroleum residues},
journal={Carbon Letters},
issn={1976-4251},
year={2015},
volume={16},
number={3},
pages={171-182}
TY - JOUR
AU - Subhash Kumar
AU - Manoj Srivastava
TI - Mesophase formation behavior in petroleum residues
JO - Carbon Letters
PY - 2015
VL - 16
IS - 3
PB - Korean Carbon Society
SP - 171
EP - 182
SN - 1976-4251
AB - Mesophase pitch is an important starting material for making a wide spectrum of industrial and advanced carbon products. It is produced by pyrolysis of petroleum residues. In this work, mesophase formation behavior in petroleum residues was studied to prepare environmentally- benign mesophase pitches, and the composition of petroleum residues and its influence on the mesophase formation was investigated. Two petroleum residues, i.e., clarified oil s (CLO-1, CLO-2) obtained from fluid catalytic cracking units of different Indian petroleum refineries, were taken as feed stocks. A third petroleum residue, aromatic extract (AE), was produced by extraction of one of the CLO-1 by using N-methyl pyrrolidone solvent. These petroleum residues were thermally treated at 380°C to examine their mesophase formation behavior. Mesophase pitches produced as a result of thermal treatment were characterized physico-chemically, as well as by instrumental techniques such as Fourier-transform infrared spectroscopy, nuclear magnetic resonance, X-ray diffraction and thermogravimetry/derivative thermogravimetry. Thermal treatment of these petroleum residues led to formation of a liquid-crystalline phase (mesophase). The mesophase formation behavior in the petroleum residues was analyzed by optical microscopy. Mesophase pitch prepared from CLO-2 exhibited the highest mesophase content (53 vol%) as compared to other mesophase pitches prepared from CLO-1 and AE.
KW - clarified oil;aromatic extract;mesophase pitch;optical microscopic analysis
DO -
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ER -
Subhash Kumar and Manoj Srivastava. (2015). Mesophase formation behavior in petroleum residues. Carbon Letters, 16(3), 171-182.
Subhash Kumar and Manoj Srivastava. 2015, "Mesophase formation behavior in petroleum residues", Carbon Letters, vol.16, no.3 pp.171-182.
Subhash Kumar, Manoj Srivastava "Mesophase formation behavior in petroleum residues" Carbon Letters 16.3 pp.171-182 (2015) : 171.
Subhash Kumar, Manoj Srivastava. Mesophase formation behavior in petroleum residues. 2015; 16(3), 171-182.
Subhash Kumar and Manoj Srivastava. "Mesophase formation behavior in petroleum residues" Carbon Letters 16, no.3 (2015) : 171-182.
Subhash Kumar; Manoj Srivastava. Mesophase formation behavior in petroleum residues. Carbon Letters, 16(3), 171-182.
Subhash Kumar; Manoj Srivastava. Mesophase formation behavior in petroleum residues. Carbon Letters. 2015; 16(3) 171-182.
Subhash Kumar, Manoj Srivastava. Mesophase formation behavior in petroleum residues. 2015; 16(3), 171-182.
Subhash Kumar and Manoj Srivastava. "Mesophase formation behavior in petroleum residues" Carbon Letters 16, no.3 (2015) : 171-182.