@article{ART002372207},
author={Parisa Monji and Reza Jahanmardi and Milad Mehranpour},
title={Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene},
journal={Carbon Letters},
issn={1976-4251},
year={2018},
volume={27},
number={1},
pages={81-89},
doi={10.5714/CL.2018.27.081}
TY - JOUR
AU - Parisa Monji
AU - Reza Jahanmardi
AU - Milad Mehranpour
TI - Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene
JO - Carbon Letters
PY - 2018
VL - 27
IS - 1
PB - Korean Carbon Society
SP - 81
EP - 89
SN - 1976-4251
AB - The present study aimed to prepare a novel efficient flame retardant additive for polypropylene.
The new flame retardant was prepared by chemical grafting of melamine to graphene oxide with the aid of thionyl chloride. Fourier-transform infrared spectroscopy and thermogravimetric analysis proved that melamine had been successfully grafted to the graphene oxide.
The modified graphene oxide was incorporated into polypropylene via solution mixing followed by anti-solvent precipitatio. Homogeneous distribution as well as exfoliation of the nanoplatelets in the polymer matrix was observed using transmission electron microscopy.
Thermogravimetric analysis showed a significant improvement in the thermo-oxidative stability of the polymer after incorporating 2 wt% of the modified graphene oxide. The modified graphene oxide also enhanced the limiting oxygen index of the polymer. However, the amount of improvement was not enough for the polymer to be ranked as a self-extinguishing material. Cone calorimetry showed that incorporating 2 wt% of the modified graphene oxide lowered total heat release and the average production rate of carbon monoxide during burning of the polymer by as much as 40 and 35%, respectively. Hence, it was concluded that the new flame retardant can retard burning of the polymer efficiently and profoundly reduce suffocation risk of exposure to burning polymer byproducts.
KW - carbon composites;combustion;infrared spectroscopy;stabilization;transmission electron microscopy
DO - 10.5714/CL.2018.27.081
ER -
Parisa Monji, Reza Jahanmardi and Milad Mehranpour. (2018). Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene. Carbon Letters, 27(1), 81-89.
Parisa Monji, Reza Jahanmardi and Milad Mehranpour. 2018, "Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene", Carbon Letters, vol.27, no.1 pp.81-89. Available from: doi:10.5714/CL.2018.27.081
Parisa Monji, Reza Jahanmardi, Milad Mehranpour "Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene" Carbon Letters 27.1 pp.81-89 (2018) : 81.
Parisa Monji, Reza Jahanmardi, Milad Mehranpour. Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene. 2018; 27(1), 81-89. Available from: doi:10.5714/CL.2018.27.081
Parisa Monji, Reza Jahanmardi and Milad Mehranpour. "Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene" Carbon Letters 27, no.1 (2018) : 81-89.doi: 10.5714/CL.2018.27.081
Parisa Monji; Reza Jahanmardi; Milad Mehranpour. Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene. Carbon Letters, 27(1), 81-89. doi: 10.5714/CL.2018.27.081
Parisa Monji; Reza Jahanmardi; Milad Mehranpour. Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene. Carbon Letters. 2018; 27(1) 81-89. doi: 10.5714/CL.2018.27.081
Parisa Monji, Reza Jahanmardi, Milad Mehranpour. Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene. 2018; 27(1), 81-89. Available from: doi:10.5714/CL.2018.27.081
Parisa Monji, Reza Jahanmardi and Milad Mehranpour. "Preparation of melamine-grafted graphene oxide and evaluation of its efficacy as a flame retardant additive for polypropylene" Carbon Letters 27, no.1 (2018) : 81-89.doi: 10.5714/CL.2018.27.081