Fabrication of carbon nanofiber electrodes using poly(acrylonitrile‑co‑vinylimidazole) and their energy storage performance

Kyung-Hye Jung (정경혜); So Jeong Kim (김소정); SON YE JI (손예지); John P. Ferraris

doi:10.1007/s42823-019-00035-x

Fabrication of carbon nanofiber electrodes using poly(acrylonitrile‑co‑vinylimidazole) and their energy storage performance

Carbon Letters
Abbr : Carbon Lett.
2019, 29(2), pp.177-182
DOI : 10.1007/s42823-019-00035-x
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : April 20, 2018
Accepted : April 8, 2019
Published : April 1, 2019

Kyung-Hye Jung ¹, So Jeong Kim ¹, SON YE JI ¹, John P. Ferraris ²

¹대구가톨릭대학교
²The University of Texas at Dallas

Accredited

ABSTRACT

For electrodes in electrochemical double-layer capacitors, carbon nanofibers (CNFs) were prepared by thermal treatment of precursor polymer nanofibers, fabricated by electrospinning. Poly(acrylonitrile-co-vinylimidazole) (PAV) was employed as a precursor polymer of carbon nanofibers due to the effective cyclization of PAV polymer chains during thermal treatment compared to a typical precursor, polyacrylonitrile (PAN). PAV solutions with different comonomer compositions were prepared and electrospun to produce precursor nanofibers. Surface images obtained from scanning electron microscopy showed that their nanofibrous structure was well preserved after carbonization. It was also confirmed that electrospun PAV nanofibers were successfully converted to carbon nanofibers after the carbonization step by Raman spectroscopy. Carbon nanofiber electrodes derived from PAV showed higher specific capacitances and energy/power densities than those from PAN, which was tested by coin-type cells. It was also shown that PAV with an acrylonitrile/vinylimidazole composition of 83:17 is most promising for the carbon nanofiber precursor exhibiting a specific capacitance of 114 F/g. Their energy and power density are 70.1 Wh/kg at 1 A/g and 9.5 W/kg at 6 A/g, respectively. In addition, pouch cells were assembled to load the higher amount of electrode materials in the cells, and a box-like cyclic voltammetry was obtained with high capacitances.

KEYWORDS

Carbon nanofibers · Carbon precursor · Electrodes · Electrospinning

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-28)

Total Citation Counts(KCI+WOS) (9) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (10) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

* References for papers published after 2023 are currently being built.

[journal] Thavasi V / 2008 / Electrospun nanofibers in energy and environmental applications / Energ Environ Sci 1 : 205~

[journal] Zhang L / 2014 / A review : carbon nanofibers from electrospun polyacrylonitrile and their applications / J Mater Sci 49 : 463~

[journal] Yoon YJ / 2001 / Catalytic growth mechanism of carbon nanofibers through chemical vapor deposition / Diam Relat Mater 10 : 1214~

[journal] Lim J-S / 2005 / Preparation of carbon nanofibers by catalytic CVD and their purification / Carbon Lett 6 : 31~

[journal] Huang ZM / 2003 / A review on polymer nanofibers by electrospinning and their applications in nanocomposites / Compos Sci Technol 63 : 2223~

[journal] Kim C / 2002 / Preparation and characterization of PAN-based web of carbon nanofibers by electrostatic spinning / Carbon Lett 3 : 210~

[journal] 정민정 / 2009 / Hydrogen Adsorption of PAN-based Porous Carbon Nanofibers using MgO as the Substrate / Carbon Letters / 한국탄소학회 10(3) : 217~220

[journal] Rahaman MSA / 2007 / A review of heat treatment on polyacrylonitrile fiber / Polym Degrad Stab 92 : 1421~

[journal] 배병철 / 2011 / The hydrogen storage capacity of metal-containing polyacrylonitrile- based electrospun carbon nanofibers / Carbon Letters / 한국탄소학회 12(3) : 171~176

[book] Rand B / 2012 / Design and control of structure of advanced carbon materials for enhanced performance, vol 374 / Springer Science & Business Media

[journal] Deng WJ / 2011 / Poly(acrylonitrile-co-1-vinylimidazole) : a new melt processable carbon fiber precursor / Polymer 52 : 622~

[journal] Faraji S / 2017 / Characterization of polyacrylonitrile, poly(acrylonitrile-co-vinyl acetate), and poly(acrylonitrile-co-itaconic acid)based activated carbon nanofibers / J Appl Polym Sci 134 : 44381~

[journal] Chen J / 2002 / Modification of polyacrylonitrile(PAN)carbon fiber precursor via post-spinning plasticization and stretching in dimethyl formamide(DMF) / Carbon 40 : 25~

[journal] Yusof N / 2012 / Post spinning and pyrolysis processes of polyacrylonitrile(PAN)-based carbon fiber and activated carbon fiber : a review / J Anal Appl Pyrol 93 : 1~

[journal] Liu J / 2015 / Effects of chemical composition and post-spinning stretching process on the morphological, structural, and thermo-chemical properties of electrospun polyacrylonitrile copolymer precursor nanofibers / Polymer 61 : 20~

[journal] Wangxi Z / 2003 / Evolution of structure and properties of PAN precursors during their conversion to carbon fibers / Carbon 41 : 2805~

[journal] Agend F / 2007 / Fabrication and electrical characterization of electrospun polyacrylonitrile-derived carbon nanofibers / J Appl Polym Sci 106 : 255~

[journal] Jung K-H / 2012 / Carbon nanofiber electrodes for supercapacitors derived from new precursor polymer : poly(acrylonitrile-co-vinylimidazole) / Electrochem Commun 23 : 149~

[journal] Burke A / 2000 / Ultracapacitors : why, how, and where is the technology / J Power Sour 91 : 37~

[journal] Shukla A / 2000 / Electrochemical supercapacitors : energy storage beyond batteries / Curr Sci 79 : 1656~

[journal] Jung K-H / 2012 / Preparation and electrochemical properties of carbon nanofibers derived from polybenzimidazole/polyimide precursor blends / Carbon 50 : 5309~

[journal] Jung K-H / 2016 / Preparation of porous carbon nanofibers derived from PBI/PLLA for supercapacitor electrodes / Nanotechnology 27 : 425708~

[journal] Wang Y / 2003 / Raman characterization of carbon nanofibers prepared using electrospinning / Synth Met 138 : 423~

[journal] Cançado L / 2006 / General equation for the determination of the crystallite size L a of nanographite by Raman spectroscopy / Appl Phys Lett 88 : 163106~

[journal] Wang X / 2016 / Geometrically confined favourable ion packing for high gravimetric capacitance in carbon–ionic liquid supercapacitors / Energy Environ Sci 9 : 232~

[journal] Tooming T / 2015 / High power density supercapacitors based on the carbon dioxide activated d-glucose derived carbon electrodes and 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid / J Power Sour 280 : 667~

[journal] Van Aken KL / 2015 / Formulation of ionic-liquid electrolyte to expand the voltage window of supercapacitors / Angew Chem Int Ed 54 : 4806~

[journal] Balducci A / 2007 / High temperature carbon–carbon supercapacitor using ionic liquid as electrolyte / J Power Sour 165 : 922~

[thesis] Cruz MED / 2012 / Development of carbon nanofibers for supercapacitor electrode applications / Doctoral / University of Texas at Dallas

[journal] Jung K-H / 2018 / Electrochemical energy storage performance of carbon nanofiber electrodes derived from 6FDA-durene / Nanotechnology 29 : 275701~

[journal] Kim C / 2003 / Electrochemical properties of carbon nanofiber web as an electrode for supercapacitor prepared by electrospinning / Appl Phys Lett 83 : 1216~

[journal] Abeykoon NC / 2015 / Supercapacitor performance of carbon nanofiber electrodes derived from immiscible PAN/PMMA polymer blends / RSC Adv 5 : 19865~

[journal] Liwen J / 2009 / Fabrication of porous carbon nanofibers and their application as anode materials for rechargeable lithium-ion batteries / Nanotechnology 20 : 155705~

[journal] Bonso JS / 2014 / High surface area carbon nanofibers derived from electrospun PIM-1 for energy storage applications / J Mater Chem A 2 : 418~

[journal] Abeykoon NC / 2017 / Novel binder-free electrode materials for supercapacitors utilizing high surface area carbon nanofibers derived from immiscible polymer blends of PBI/6FDA-DAM : DABA / RSC Adv 7 : 20947~

[journal] Kim C / 2005 / Electrochemical characterization of electrospun activated carbon nanofibres as an electrode in supercapacitors / J Power Sour 142 : 382~

[journal] Tsai JS / 1991 / Effect of comonomer composition on the properties of polyacrylonitrile precursor and resulting carbon fiber / J Appl Polym Sci 43 : 679~

[journal] Nguyen-Thai NU / 2014 / Controlled architectures of poly(acrylonitrile-co-itaconic acid)for efficient structural transformation into carbon materials / Carbon 69 : 571~

[journal] Cetiner S / 2013 / Acrylonitrile/vinyl acetate copolymer nanofibers with different vinylacetate content / J Appl Polym Sci 127 : 3830~

KJCKorea
Journal Central

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Fabrication of carbon nanofiber electrodes using poly(acrylonitrile‑co‑vinylimidazole) and their energy storage performance

ABSTRACT

KEYWORDS

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-28)

Total Citation Counts(KCI+WOS) (9) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (10) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Fabrication of carbon nanofiber electrodes using poly(acrylonitrile‑co‑vinylimidazole) and their energy storage performance

ABSTRACT

KEYWORDS

Statistics

Tools

Issue List

Citation status

KCI Citation Counts (3)

WoS Citation Counts (6) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-28)

Total Citation Counts(KCI+WOS) (9) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (10) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

REFERENCES (39) * References for papers published after 2023 are currently being built.

Search PDF

Citation

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-28)

* References for papers published after 2023 are currently being built.