@article{ART002695546},
author={Cho Jong Hoon and Im Ji Sun and Kim Min Il and Lee, Young-Seak and Bai Byong Chol},
title={Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch},
journal={Carbon Letters},
issn={1976-4251},
year={2020},
volume={30},
number={4},
pages={373-379},
doi={10.1007/s42823-019-00106-z}
TY - JOUR
AU - Cho Jong Hoon
AU - Im Ji Sun
AU - Kim Min Il
AU - Lee, Young-Seak
AU - Bai Byong Chol
TI - Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch
JO - Carbon Letters
PY - 2020
VL - 30
IS - 4
PB - Korean Carbon Society
SP - 373
EP - 379
SN - 1976-4251
AB - In the present study, carbon molded bodies were prepared by using graphite/coke fllers and petroleum-based binder pitch with various softening points, and the thermal properties of the prepared carbon molded bodies were investigated. The ratio of a binder afects the molded body preparation: no molded body was prepared at a low binder pitch content, and swelling occurred during the thermal treatment at a high binder pitch content. The binder pitch thermal treatment yield was the high�est at 41 wt% at the softening point of 150 °C and the lowest at 23 wt% at the softening point of 78 °C. A signifcant mass reduction was found in the range of 150 to 300 °C in the petroleum-based binder pitch, and in the range of 300 to 475 °C in the coal-based binder pitch. The molecular weight of the binder pitch was analyzed through the matrix-assisted laser desorption/ionization time-of-fight (MALDI-TOF) method. The molecular weight ratio within the interval showing the highest binder pitch molecular weight (178 to 712 m/z) was the highest at 66.4% in the coal-based binder pitch (softening point 115 °C) and the lowest at 46.0% in the petroleum-based binder pitch (softening point 116 °C). When the petroleum�based binder pitch was applied, as the softening point was increased, the voids decreased and thus the thermal conductivity increased. The highest thermal conductivity was 99.5 W/mK for the carbon molded bodies prepared using the coal-based binder pitch and 102.8 W/mK for those prepared by using the petroleum-based binder pitch. The results showed that the thermal properties were similar between the coal-based binder pitch (softening point 115 °C) and the petroleum-based binder pitch (softening point 150 °C).
KW - Pitch · Softening point · Graphite block · Thermal conductivity
DO - 10.1007/s42823-019-00106-z
ER -
Cho Jong Hoon, Im Ji Sun, Kim Min Il, Lee, Young-Seak and Bai Byong Chol. (2020). Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch. Carbon Letters, 30(4), 373-379.
Cho Jong Hoon, Im Ji Sun, Kim Min Il, Lee, Young-Seak and Bai Byong Chol. 2020, "Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch", Carbon Letters, vol.30, no.4 pp.373-379. Available from: doi:10.1007/s42823-019-00106-z
Cho Jong Hoon, Im Ji Sun, Kim Min Il, Lee, Young-Seak, Bai Byong Chol "Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch" Carbon Letters 30.4 pp.373-379 (2020) : 373.
Cho Jong Hoon, Im Ji Sun, Kim Min Il, Lee, Young-Seak, Bai Byong Chol. Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch. 2020; 30(4), 373-379. Available from: doi:10.1007/s42823-019-00106-z
Cho Jong Hoon, Im Ji Sun, Kim Min Il, Lee, Young-Seak and Bai Byong Chol. "Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch" Carbon Letters 30, no.4 (2020) : 373-379.doi: 10.1007/s42823-019-00106-z
Cho Jong Hoon; Im Ji Sun; Kim Min Il; Lee, Young-Seak; Bai Byong Chol. Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch. Carbon Letters, 30(4), 373-379. doi: 10.1007/s42823-019-00106-z
Cho Jong Hoon; Im Ji Sun; Kim Min Il; Lee, Young-Seak; Bai Byong Chol. Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch. Carbon Letters. 2020; 30(4) 373-379. doi: 10.1007/s42823-019-00106-z
Cho Jong Hoon, Im Ji Sun, Kim Min Il, Lee, Young-Seak, Bai Byong Chol. Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch. 2020; 30(4), 373-379. Available from: doi:10.1007/s42823-019-00106-z
Cho Jong Hoon, Im Ji Sun, Kim Min Il, Lee, Young-Seak and Bai Byong Chol. "Preparation of petroleum-based binder pitch for manufacturing thermally conductive carbon molded body and comparison with commercial coal-based binder pitch" Carbon Letters 30, no.4 (2020) : 373-379.doi: 10.1007/s42823-019-00106-z