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Uniform deposition of large-area graphene films on copper using low-pressure chemical vapor deposition technique

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2022, 32(3), pp.781-787
  • DOI : 10.1007/s42823-021-00309-3
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : August 17, 2021
  • Accepted : November 16, 2021
  • Published : May 1, 2022

Gürsoy Mehmet 1 Çıtak Emre 2 Karaman Mustafa 1

1Nanotechnology and Advanced Materials Development Application and Research Center, Konya Technical University
2Department of Chemical Engineering, Konya Technical University

Accredited

ABSTRACT

Large-area graphene of the order of centimeters was deposited on copper substrates by low-pressure chemical vapor deposition (LPCVD) using hexane as the carbon source. The effect of temperature and the carrier gas flowrates on the quality and uniformity of the as-deposited graphene was investigated using the Raman analysis. The film deposited at 870 °C with a total carrier gas flowrate of 50 sccm is predominantly single-layer with very low defects according to the Raman spectra. The 2D/G peak intensity ratios obtained from the Raman spectra of samples from three different locations of graphene deposited on a whole copper catalyst was used to calculate the large-area uniformity. Based on the results, a very high uniformity of 89.6% was calculated for the graphene deposited at 870 °C. The uniformity was observed to decrease with increasing temperature. Similar to the thickness uniformity, the electrical conductivity values obtained as a result of I–V measurements and water contact angle measurements were found to be close to each other for the graphene deposited under the same deposition conditions.

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