Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04
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pISSN : 1976-4251 / eISSN : 2233-4998
- https://journal.kci.go.kr/carbon
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Synthesis and characterization of ethylenediamine functionalized graphene oxide-modified UiO-66-NH2 for quinoline removal
- Carbon Letters
- Abbr : Carbon Lett.
- 2022, 32(7), pp.1689-1702
- DOI : 10.1007/s42823-022-00370-6
- Publisher : Korean Carbon Society
- Research Area : Natural Science > Natural Science General > Other Natural Sciences General
- Received : April 30, 2022
- Accepted : June 22, 2022
- Published : December 1, 2022
Mokgohloa Mathule 1, Ogunlaja Adeniyi S. 1
1Department of Chemistry, Nelson Mandela University
Accredited
ABSTRACT
In this study, UiO-66-NH2 was synthesized and incorporated with graphene aerosol (UiO-66-NH2/GA) and ethylenediamine functionalized graphene oxide (UiO-66-NH2/GO-NH2). These composites were characterized using infrared spectroscopy, powder X-ray diffraction, ultraviolet–visible light spectroscopy, scanning electron microscope, and energy-dispersive X-ray spectroscopy. UiO-66-NH2/GO-NH2 exhibited 93% adsorption of quinoline in 5 h, UiO-66-NH2 and UiO-66-NH2/GA presented 80.4% and 86.5%, respectively. The high adsorption observed on UiO-66-NH2/GO-NH2 was attributed to the unique electronic properties, and hydrogen bonding between the nitrogen atom of quinoline and NH2-phenyl fragment of UiO-66-NH2, and N–H of ethylenediamine. GO also offered combined strong π–π interactions on its surface, and the oxygen coverage (~ 50%) on GO within the structure is responsible for the formation of strong hydrogen bonds with quinoline. Theoretical calculation suggested that UiO-66-NH2/GO-NH2 presented a more favourable adsorption energy (− 18.584 kcal/mol) compared to UiO-66-NH2 (− 16.549 kcal/mol) and UiO-66-NH2/GA (− 13.991 kcal/mol). These results indicate that nanocomposites have a potential application in quinoline capture technologies in the process of adsorptive denitrogenation.
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This paper was written with support from the National Research Foundation of Korea.