Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04
-
pISSN : 1976-4251 / eISSN : 2233-4998
- https://journal.kci.go.kr/carbon
KJCKorea
Journal Central
Synthesis and characterization of ethylenediamine functionalized graphene oxide-modified UiO-66-NH2 for quinoline removal
- Carbon Letters
- Abbr : Carbon Lett.
- 2022, 32(7), pp.1689-1702
- DOI : 10.1007/s42823-022-00370-6
- Publisher : Korean Carbon Society
- Research Area : Natural Science > Natural Science General > Other Natural Sciences General
- Received : April 30, 2022
- Accepted : June 22, 2022
- Published : December 1, 2022
Mokgohloa Mathule 1, Ogunlaja Adeniyi S. 1
1Department of Chemistry, Nelson Mandela University
Accredited
ABSTRACT
In this study, UiO-66-NH2 was synthesized and incorporated with graphene aerosol (UiO-66-NH2/GA) and ethylenediamine functionalized graphene oxide (UiO-66-NH2/GO-NH2). These composites were characterized using infrared spectroscopy, powder X-ray diffraction, ultraviolet–visible light spectroscopy, scanning electron microscope, and energy-dispersive X-ray spectroscopy. UiO-66-NH2/GO-NH2 exhibited 93% adsorption of quinoline in 5 h, UiO-66-NH2 and UiO-66-NH2/GA presented 80.4% and 86.5%, respectively. The high adsorption observed on UiO-66-NH2/GO-NH2 was attributed to the unique electronic properties, and hydrogen bonding between the nitrogen atom of quinoline and NH2-phenyl fragment of UiO-66-NH2, and N–H of ethylenediamine. GO also offered combined strong π–π interactions on its surface, and the oxygen coverage (~ 50%) on GO within the structure is responsible for the formation of strong hydrogen bonds with quinoline. Theoretical calculation suggested that UiO-66-NH2/GO-NH2 presented a more favourable adsorption energy (− 18.584 kcal/mol) compared to UiO-66-NH2 (− 16.549 kcal/mol) and UiO-66-NH2/GA (− 13.991 kcal/mol). These results indicate that nanocomposites have a potential application in quinoline capture technologies in the process of adsorptive denitrogenation.
Statistics
-
170 Viewed
-
1 Downloaded
Tools
Issue List
Citation status
This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)
Total Citation Counts(KCI+WOS) (3) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.
Scopus Citation Counts (4) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)
* References for papers published after 2023 are currently being built.
[journal]
Deese RD
/ 2019
/ The characterization of organic nitrogen compounds and their impact on the stability of marginally stable diesel fuels
/ Energy Fuels
33(7)
: 6659~6669
[journal]
Zhang ED
/ 2010
/ Adsorptive removal of nitrogen-containing compounds from fuel
/ J Chem Eng Data
55
: 173~177
[journal]
Driscoll C
/ 2003
/ Nitrogen pollution : sources and consequences in the US Northeast
/ Environ Sci Policy
45(7)
: 8~22
[journal]
Zhu J
/ 2019
/ Polyethyleneimine-modified UiO-66-NH2(Zr)metal-organic frameworks : preparation and enhanced CO2selective adsorption
/ ACS Omega
4(2)
: 3188~3197
[journal]
Cao Y
/ 2018
/ UiO-66-NH2/GO composite : synthesis, characterization and CO2adsorption performance
/ Materials
11(11)
: 589~
[journal]
Kim MJ
/ 2011
/ Adsorption of pyridine onto the metal organic framework MIL-101
/ J Colloid Interface Sci
361
: 612~617
[journal]
Mambrini RV
/ 2013
/ Adsorption of sulfur and nitrogen compounds on hydrophobic bentonite
/ Appl Clay Sci
83–84
: 286~293
[journal]
Sano Y
/ 2004
/ Adsorptive removal of sulfur and nitrogen species from a straight run gas oil over activated carbons for its deep hydrodesulfurization
/ Appl Catal B Environ
49
: 219~225
[journal]
Ahmed I
/ 2015
/ Remarkable improvement in adsorptive denitrogenation of model fossil fuels with CuCl/activated carbon, prepared under ambient condition
/ Chem Eng J
279(1)
: 327~334
[journal]
Kwon JM
/ 2008
/ Adsorptive desulfurization and denitrogenation of refinery fuels using mesoporous silica adsorbents
/ Chemsuschem
1(4)
: 307~309
[journal]
Maldonado AJH
/ 2004
/ Denitrogenation of transportation fuels by zeolites at ambient temperature and pressure
/ Angew Chem Int Ed
43(8)
: 1004~1006
[journal]
Tian F
/ 2020
/ Effective adsorptive denitrogenation from model fuels over yttrium ion-exchanged Y zeolite
/ Chin J Chem Eng
28(2)
: 414~419
[journal]
Ofoghi S
/ 2022
/ Quinoline adsorption from organic phase on X-type zeolites : experimental and DFT study
/ Can J Chem Eng
100(4)
: 838~848
[journal]
Chavan SM
/ 2014
/ Synthesis and characterization of amine-functionalized mixed-ligand metal-organic frameworks of UiO-66 topology
/ Inorg Chem
53(18)
: 9509~9515
[journal]
Wiersum AD
/ 2011
/ Llewellyn, an evaluation of UiO-66 for gas-based applications
/ Chem Asian
6(12)
: 3270~3280
[journal]
Sumida K
/ 2012
/ Carbon dioxide capture in metal-organic frameworks
/ Chem Rev
112(2)
: 724~781
[journal]
Cliffe MJ
/ 2014
/ Correlation defect nanoregions in a metal-organic framework
/ Nat Commun
5
: 4176~
[journal]
Yang Q
/ 2011
/ Understanding the thermodynamic and kinetic behavior of the CO2/CH4 gas mixture within the porous zirconium terephthalate UiO-66(Zr) : a joint experimental and modelling approach
/ J Phys Chem C
115(28)
: 13768~13774
[journal]
Kronast A
/ 2016
/ Gated channels and selectivity tuning of CO2over N2sorption by post-synthetic modification of a UiO-66-type metal-organic framework
/ Chem Eur J
22
: 1~9
[journal]
Cmarik GE
/ 2012
/ Tuning the adsorption properties of UiO-66 via ligand functionalization
/ Langmuir
28(44)
: 15606~15613
[journal]
Kandiah M
/ 2010
/ Synthesis and stability of tagged UiO-66 Zr-MOFs
/ Chem Mater
22(24)
: 6632~6640
[book]
Choi W
/ 2017
/ Nanomaterials and their applications;graphene synthesis and applications
/ CRC Press
[journal]
Eltaweil AS
/ 2021
/ Ultra-high adsorption capacity and selective removal of Congo red over aminated graphene oxide modified Mn-Doped UiO-66MOF
/ Powder Technol
379
: 407~416
[journal]
Omer AM
/ 2022
/ Novel reusable amine-functionalized cellulose acetate beads impregnated aminated graphene oxide for adsorptive removal of hexavalent chromium ions
/ Int J Biol Macromol
206
: 925~934
[journal]
Paulchamy B
/ 2015
/ A simple approach to stepwise synthesis of graphene oxide nanomaterial
/ J Nanomed Nanotechnol
6(1)
: 1~4
[journal]
Wu ZS
/ 2012
/ 3D Nitrogen-doped graphene aerogel-supported Fe3O4nanoparticles as efficient electrocatalysts for the oxygen reduction reaction
/ J Am Chem Soc
134(22)
: 9082~9085
[journal]
Zhang X
/ 2018
/ Modular preparation of graphene-base functional architectures through two-step organic reactions : towards high-performance energy storage
/ Chem Eur J
24(69)
: 18518~18528
[journal]
Ogunlaja AS
/ 2014
/ The adsorptive extraction of oxidised sulfur-containing compounds from fuels by using molecularly imprinted chitosan materials
/ React Funct Polym
81
: 61~76
[journal]
Ogunlaja AS
/ 2014
/ Design, fabrication and evaluation of intelligent sulfone-selective polybenzimidazole nanofibers
/ Talanta
126
: 61~72
[journal]
Xu H
/ 2019
/ Removal of quinoline using various particle sizes anthracite : adsorption kinetics and adsorption isotherms
/ Physicochem Probl Miner Process
55(1)
: 196~207
[journal]
Mohan SV
/ 1997
/ Removal of lignin and tannin colour from aqueous solution by adsorption onto activated charcoal
/ Environ Pollut
97(1–2)
: 183~187
[book]
Stewart JJP
/ 2020
/ SCIGRESS, Version FO 3.5.0
/ Fujitsu Limited
[journal]
Hay PJ
/ 1985
/ Abinitio effective core potentials for molecular calculations—potentials for the transition-metal atoms Sc to Hg
/ J Chem Phys
82(1)
: 270~283
[journal]
Hay PJ
/ 1985
/ Abinitio effective core potentials for molecular calculations—potentials for K to Au including the outermost core orbitals
/ J Chem Phys
82(1)
: 299~310
[journal]
Wadt WR
/ 1985
/ Abinitio effective core potentials for molecular calculations—potentials for main group elements Na to Bi
/ J Chem Phys
82
: 284~298
[journal]
Saravanan S
/ 2014
/ Quantum chemical studies, natural bond orbital analysis and thermodynamic function of 2, 5-dichlorophenylisocyanate
/ Spectrochim Acta Part A Mol Biomol Spectrosc
120
: 351~365
[journal]
Politzer P
/ 1998
/ A comparative analysis of Hartree-Fock and Kohn-Sham orbital energies
/ Theor Chem Acc
99(2)
: 83~87
[journal]
Mulliken RS
/ 1934
/ A new electroaffinity scale; together with data on valence states and on valence ionization potentials and electron affinities
/ J Chem Phys
2(11)
: 782~793
[book]
Hoffmann R
/ 1988
/ Solids and surfaces: a chemist’s view of bonding in extended structures
/ VCH Publishers
[journal]
Parr RG
/ 1999
/ Electrophilicity index
/ J Am Chem Soc
121(9)
: 1922~1924
[journal]
Padmanabhan J
/ 2007
/ Electrophilicity-based charge transfer descriptor
/ J Phys Chem A
111(7)
: 1358~1369
[journal]
Shahriary L
/ 2014
/ Graphene oxide synthesized by using modified hummers approach
/ Int J Renew Energy Environ
2
: 58~63
[journal]
Park J
/ 2014
/ Photochromic metalorganic frameworks : reversible control of singlet oxygen generation
/ Angew Chem Int Ed Engl
53
: 1~6
[journal]
Makula P
/ 2018
/ How to correctly determine the band gap energy of modified semiconductor photocatalysts based On UV–Vis spectra
/ J Phys Chem Lett
9(23)
: 6814~6817
[journal]
Motegi H
/ 2017
/ A facile synthesis of Uio-66 systems and their hydrothermal stability
/ J Porous Mater
24
: 1327~1333
[journal]
Rouquerol J
/ 2007
/ Is the BET equation applicable to microporous adsorbents?
/ Stud Surf Sci Catal
160
: 49~56
[journal]
Wang JC
/ 2016
/ Cu(ii)/Cu(0)@UiO-66-NH2 : base metal@Mofs as heterogeneous catalysts for olefin oxidation and reduction
/ Chem Commun
52(89)
: 13116~13119
[journal]
Ka D
/ 2021
/ Uio-66-NH2/graphene oxide nanocomposites as reactive adsorbents for soman upon long-term exposure to high-humidity environment
/ Mater Lett
285
: 129105~
[journal]
Feng X
/ 2015
/ Adsorption of quinoline from liquid hydrocarbons on graphite oxide and activated carbons
/ RSC Adv
5
: 74684~74691
[journal]
Wang L
/ 2020
/ Improved removal of quinoline from wastewater using coke powder with inorganic ions
/ Processes
8(2)
: 156~
[journal]
Ferreira MEO
/ 2019
/ Modified activated carbon as a promising adsorbent for quinoline removal
/ Microporous Mesoporous Mater
277
: 208~216
[journal]
Bian Y
/ 2018
/ Effect of inorganic salt ions on the adsorption of quinoline using coal powder
/ Processes
78(3)
: 495~505
[journal]
Sarker M
/ 2018
/ Adsorptive removal of indole and quinoline from model fuel over various UiO-66s : quantitative contributions of H-bonding and acid-base interactions to adsorption
/ J Phys Chem C
122
: 4532~4539
[journal]
Ogunlaja AS
/ 2014
/ Dispersion of asphaltenes in petroleum with ionic liquids-evaluation of molecular interactions in the binary mixture
/ Ind Eng Chem Res
53(48)
: 18390~18401
This paper was written with support from the National Research Foundation of Korea.