Designing of 3D porous silicon/carbon complex anode based on metal-organic frameworks for lithium-ion battery

Ahn Won Jun; Park Byeong Hyeon; Seo Sang Wan; Kim Seok; Im Ji Sun

doi:10.1007/s42823-023-00572-6

Designing of 3D porous silicon/carbon complex anode based on metal-organic frameworks for lithium-ion battery

Carbon Letters
Abbr : Carbon Lett.
2023, 33(7), pp.2349-2361
DOI : 10.1007/s42823-023-00572-6
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : May 24, 2023
Accepted : July 4, 2023
Published : December 1, 2023

Ahn Won Jun ¹, Park Byeong Hyeon ², Seo Sang Wan ¹, Kim Seok ², Im Ji Sun ¹

¹C1 Gas & Carbon Convergent Research, Korea Research Institute of Chemical Technology, Daejeon, 34114, Republic of Korea
²Department of Chemical and Biomolecular Engineering, Pusan National University, Geumjeong-gu, Busan, 46241, Republic of Korea

Accredited

ABSTRACT

The complexation of silicon with carbon materials is considered an effective method for using silicon as an anode material for lithium-ion batteries. In the present study, carbon frameworks with a 3D porous structure were fabricated using metal–organic frameworks (MOFs), which have been drawing significant attention as a promising material in a wide range of applications. Subsequently, the fabricated carbon frameworks were subjected to CVD to obtain silicon-carbon complexes. These silicon-carbon complexes with a 3D porous structure exhibited excellent rate capability because they provided sufficient paths for Li-ion diffusion while facilitating contact with the electrolyte. In addition, unoccupied space within the silicon complex, combined with the stable structure of the carbon framework, allowed the volume expansion of silicon and the resultant stress to be more effectively accommodated, thereby reducing electrode expansion. The major findings of the present study demonstrate the applicability of MOF-based carbon frameworks as a material for silicon complex anodes.

KEYWORDS

Metal organic framework Silicon Carbon Anode Lithium-ion battery

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Designing of 3D porous silicon/carbon complex anode based on metal-organic frameworks for lithium-ion battery

ABSTRACT

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Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (3) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (2) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Designing of 3D porous silicon/carbon complex anode based on metal-organic frameworks for lithium-ion battery

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WoS Citation Counts (3) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (3) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (2) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

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This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

* References for papers published after 2023 are currently being built.