@article{ART003241386},
author={Liu Liuliu and Chen Keqi and Zhang Keyu and Jiang Xinyu and Yan Rui and Zhang Shaoze and Li Yin and Hu Junxian and Yang Bin and Yao Yaochun},
title={State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications},
journal={Carbon Letters},
issn={1976-4251},
year={2025},
volume={35},
number={3},
pages={987-1015},
doi={10.1007/s42823-025-00904-8}
TY - JOUR
AU - Liu Liuliu
AU - Chen Keqi
AU - Zhang Keyu
AU - Jiang Xinyu
AU - Yan Rui
AU - Zhang Shaoze
AU - Li Yin
AU - Hu Junxian
AU - Yang Bin
AU - Yao Yaochun
TI - State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications
JO - Carbon Letters
PY - 2025
VL - 35
IS - 3
PB - Korean Carbon Society
SP - 987
EP - 1015
SN - 1976-4251
AB - Biochar is considered as key anode material for alkali metal (lithium, sodium, and potassium) ion batteries (AIBs) owing to its rich microstructural features, high specific surface area, active sites, excellent conductivity, and mechanical strength. The multidimensional structures and diverse functional groups of biochar make it enable easy modification to improve ion transport, interface deposition behavior, and electrolyte stability. In addition, biochar-based derivatives, such as silicon/biochar composite anode materials, combine the advantages of high-energy density and low lithiation potential of silicon materials, as well as the superior conductive ability and outstanding mechanical qualities of biochar. In this review, the microstructure, properties, and synthesis methods of biochar materials are systematically clarified, and then, their applications in AIBs are presented followed by summarizing the energy storage mechanism and advanced physicochemical characterizations. Common structural configurations and preparative technique for biochar/silicon-based composites are summarized, such as core–shell, yolk–shell, and embedded coating structures with improved electrochemical and mechanical stability. Finally, toward practical application of biochar and biochar-based derivatives in future AIBs, the issues and challenges are outlined.
KW - Biochar;Silicon-based materials;Alkali metal ion batteries;Structural design;Electrochemical energy storage
DO - 10.1007/s42823-025-00904-8
ER -
Liu Liuliu, Chen Keqi, Zhang Keyu, Jiang Xinyu, Yan Rui, Zhang Shaoze, Li Yin, Hu Junxian, Yang Bin and Yao Yaochun. (2025). State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. Carbon Letters, 35(3), 987-1015.
Liu Liuliu, Chen Keqi, Zhang Keyu, Jiang Xinyu, Yan Rui, Zhang Shaoze, Li Yin, Hu Junxian, Yang Bin and Yao Yaochun. 2025, "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications", Carbon Letters, vol.35, no.3 pp.987-1015. Available from: doi:10.1007/s42823-025-00904-8
Liu Liuliu, Chen Keqi, Zhang Keyu, Jiang Xinyu, Yan Rui, Zhang Shaoze, Li Yin, Hu Junxian, Yang Bin, Yao Yaochun "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications" Carbon Letters 35.3 pp.987-1015 (2025) : 987.
Liu Liuliu, Chen Keqi, Zhang Keyu, Jiang Xinyu, Yan Rui, Zhang Shaoze, Li Yin, Hu Junxian, Yang Bin, Yao Yaochun. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. 2025; 35(3), 987-1015. Available from: doi:10.1007/s42823-025-00904-8
Liu Liuliu, Chen Keqi, Zhang Keyu, Jiang Xinyu, Yan Rui, Zhang Shaoze, Li Yin, Hu Junxian, Yang Bin and Yao Yaochun. "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications" Carbon Letters 35, no.3 (2025) : 987-1015.doi: 10.1007/s42823-025-00904-8
Liu Liuliu; Chen Keqi; Zhang Keyu; Jiang Xinyu; Yan Rui; Zhang Shaoze; Li Yin; Hu Junxian; Yang Bin; Yao Yaochun. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. Carbon Letters, 35(3), 987-1015. doi: 10.1007/s42823-025-00904-8
Liu Liuliu; Chen Keqi; Zhang Keyu; Jiang Xinyu; Yan Rui; Zhang Shaoze; Li Yin; Hu Junxian; Yang Bin; Yao Yaochun. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. Carbon Letters. 2025; 35(3) 987-1015. doi: 10.1007/s42823-025-00904-8
Liu Liuliu, Chen Keqi, Zhang Keyu, Jiang Xinyu, Yan Rui, Zhang Shaoze, Li Yin, Hu Junxian, Yang Bin, Yao Yaochun. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. 2025; 35(3), 987-1015. Available from: doi:10.1007/s42823-025-00904-8
Liu Liuliu, Chen Keqi, Zhang Keyu, Jiang Xinyu, Yan Rui, Zhang Shaoze, Li Yin, Hu Junxian, Yang Bin and Yao Yaochun. "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications" Carbon Letters 35, no.3 (2025) : 987-1015.doi: 10.1007/s42823-025-00904-8