@article{ART003241386},
author={Liuliu Liu and Keqi Chen and Keyu Zhang and Xinyu Jiang and Rui Yan and Shaoze Zhang and Yin Li and Junxian Hu and Bin Yang and Yaochun Yao},
title={State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications},
journal={Carbon Letters},
issn={1976-4251},
year={2025},
volume={35},
number={3},
pages={987-1015},
doi={10.1007/s42823-025-00904-8}
TY - JOUR
AU - Liuliu Liu
AU - Keqi Chen
AU - Keyu Zhang
AU - Xinyu Jiang
AU - Rui Yan
AU - Shaoze Zhang
AU - Yin Li
AU - Junxian Hu
AU - Bin Yang
AU - Yaochun Yao
TI - State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications
JO - Carbon Letters
PY - 2025
VL - 35
IS - 3
PB - Korean Carbon Society
SP - 987
EP - 1015
SN - 1976-4251
AB - Biochar is considered as key anode material for alkali metal (lithium, sodium, and potassium) ion batteries (AIBs) owing to its rich microstructural features, high specific surface area, active sites, excellent conductivity, and mechanical strength. The multidimensional structures and diverse functional groups of biochar make it enable easy modification to improve ion transport, interface deposition behavior, and electrolyte stability. In addition, biochar-based derivatives, such as silicon/biochar composite anode materials, combine the advantages of high-energy density and low lithiation potential of silicon materials, as well as the superior conductive ability and outstanding mechanical qualities of biochar. In this review, the microstructure, properties, and synthesis methods of biochar materials are systematically clarified, and then, their applications in AIBs are presented followed by summarizing the energy storage mechanism and advanced physicochemical characterizations. Common structural configurations and preparative technique for biochar/silicon-based composites are summarized, such as core–shell, yolk–shell, and embedded coating structures with improved electrochemical and mechanical stability. Finally, toward practical application of biochar and biochar-based derivatives in future AIBs, the issues and challenges are outlined.
KW - Biochar;Silicon-based materials;Alkali metal ion batteries;Structural design;Electrochemical energy storage
DO - 10.1007/s42823-025-00904-8
ER -
Liuliu Liu, Keqi Chen, Keyu Zhang, Xinyu Jiang, Rui Yan, Shaoze Zhang, Yin Li, Junxian Hu, Bin Yang and Yaochun Yao. (2025). State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. Carbon Letters, 35(3), 987-1015.
Liuliu Liu, Keqi Chen, Keyu Zhang, Xinyu Jiang, Rui Yan, Shaoze Zhang, Yin Li, Junxian Hu, Bin Yang and Yaochun Yao. 2025, "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications", Carbon Letters, vol.35, no.3 pp.987-1015. Available from: doi:10.1007/s42823-025-00904-8
Liuliu Liu, Keqi Chen, Keyu Zhang, Xinyu Jiang, Rui Yan, Shaoze Zhang, Yin Li, Junxian Hu, Bin Yang, Yaochun Yao "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications" Carbon Letters 35.3 pp.987-1015 (2025) : 987.
Liuliu Liu, Keqi Chen, Keyu Zhang, Xinyu Jiang, Rui Yan, Shaoze Zhang, Yin Li, Junxian Hu, Bin Yang, Yaochun Yao. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. 2025; 35(3), 987-1015. Available from: doi:10.1007/s42823-025-00904-8
Liuliu Liu, Keqi Chen, Keyu Zhang, Xinyu Jiang, Rui Yan, Shaoze Zhang, Yin Li, Junxian Hu, Bin Yang and Yaochun Yao. "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications" Carbon Letters 35, no.3 (2025) : 987-1015.doi: 10.1007/s42823-025-00904-8
Liuliu Liu; Keqi Chen; Keyu Zhang; Xinyu Jiang; Rui Yan; Shaoze Zhang; Yin Li; Junxian Hu; Bin Yang; Yaochun Yao. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. Carbon Letters, 35(3), 987-1015. doi: 10.1007/s42823-025-00904-8
Liuliu Liu; Keqi Chen; Keyu Zhang; Xinyu Jiang; Rui Yan; Shaoze Zhang; Yin Li; Junxian Hu; Bin Yang; Yaochun Yao. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. Carbon Letters. 2025; 35(3) 987-1015. doi: 10.1007/s42823-025-00904-8
Liuliu Liu, Keqi Chen, Keyu Zhang, Xinyu Jiang, Rui Yan, Shaoze Zhang, Yin Li, Junxian Hu, Bin Yang, Yaochun Yao. State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications. 2025; 35(3), 987-1015. Available from: doi:10.1007/s42823-025-00904-8
Liuliu Liu, Keqi Chen, Keyu Zhang, Xinyu Jiang, Rui Yan, Shaoze Zhang, Yin Li, Junxian Hu, Bin Yang and Yaochun Yao. "State-of-the-art evolution of biochar in alkali metal ion (Li, Na, K) batteries’ applications" Carbon Letters 35, no.3 (2025) : 987-1015.doi: 10.1007/s42823-025-00904-8