@article{ART003273332},
author={Kang Yingbo and Zhang Hai and Weng Yinglong and Han Xiaotong and Zhang Jianping and Huang Tingting and Li Zhefeng},
title={Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery},
journal={Carbon Letters},
issn={1976-4251},
year={2025},
volume={35},
number={4},
pages={1589-1597},
doi={10.1007/s42823-025-00873-y}
TY - JOUR
AU - Kang Yingbo
AU - Zhang Hai
AU - Weng Yinglong
AU - Han Xiaotong
AU - Zhang Jianping
AU - Huang Tingting
AU - Li Zhefeng
TI - Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery
JO - Carbon Letters
PY - 2025
VL - 35
IS - 4
PB - Korean Carbon Society
SP - 1589
EP - 1597
SN - 1976-4251
AB - All-vanadium redox flow battery (VRFB) has been considered as a promising candidate for the construction of renewable energy storage system. Expanded graphite possesses immense potential for use as typical bipolar plates in VRFB stacks. Nevertheless, the pure expanded graphite bipolar plates suffer from severe swelling in electrolyte, resulting in the losses of mechanical stability and electrical conductivity, thus leading to the efficiency decay within several cycles. Herein, we present a “nanoglue” strategy for tuning the structure/surface properties of expanded graphite by employing polyvinylidene fluoride (PVDF) polymer as structural sealant. Such PVDF “nanoglue” on expanded graphite results in the fine-repairment toward the surface microcracks and cross-section edges, which is beneficial to suppress the electrolyte permeation and improve the anti-swelling capacity. Moreover, it has been found that the PVDF “nanoglue” can improve the flexibility, allowing for the fabrication of ultrathin bipolar plates (0.67 mm) with low electrical resistivity. Benefiting from these integrated characteristics, the VRFB employing the as-fabricated composite bipolar plates delivers excellent cyclic efficiencies (voltage efficiency, coulombic efficiency, and energy efficiency) and ultralow ohmic voltage loss of less than 1.1 mV (< 0.1% of the VRFB rated voltage of 1.25 V) at a high current density of 200 mA cm−2.
KW - Redox flow battery;Bipolar plate;Expanded graphite;PVDF;Composite
DO - 10.1007/s42823-025-00873-y
ER -
Kang Yingbo, Zhang Hai, Weng Yinglong, Han Xiaotong, Zhang Jianping, Huang Tingting and Li Zhefeng. (2025). Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery. Carbon Letters, 35(4), 1589-1597.
Kang Yingbo, Zhang Hai, Weng Yinglong, Han Xiaotong, Zhang Jianping, Huang Tingting and Li Zhefeng. 2025, "Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery", Carbon Letters, vol.35, no.4 pp.1589-1597. Available from: doi:10.1007/s42823-025-00873-y
Kang Yingbo, Zhang Hai, Weng Yinglong, Han Xiaotong, Zhang Jianping, Huang Tingting, Li Zhefeng "Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery" Carbon Letters 35.4 pp.1589-1597 (2025) : 1589.
Kang Yingbo, Zhang Hai, Weng Yinglong, Han Xiaotong, Zhang Jianping, Huang Tingting, Li Zhefeng. Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery. 2025; 35(4), 1589-1597. Available from: doi:10.1007/s42823-025-00873-y
Kang Yingbo, Zhang Hai, Weng Yinglong, Han Xiaotong, Zhang Jianping, Huang Tingting and Li Zhefeng. "Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery" Carbon Letters 35, no.4 (2025) : 1589-1597.doi: 10.1007/s42823-025-00873-y
Kang Yingbo; Zhang Hai; Weng Yinglong; Han Xiaotong; Zhang Jianping; Huang Tingting; Li Zhefeng. Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery. Carbon Letters, 35(4), 1589-1597. doi: 10.1007/s42823-025-00873-y
Kang Yingbo; Zhang Hai; Weng Yinglong; Han Xiaotong; Zhang Jianping; Huang Tingting; Li Zhefeng. Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery. Carbon Letters. 2025; 35(4) 1589-1597. doi: 10.1007/s42823-025-00873-y
Kang Yingbo, Zhang Hai, Weng Yinglong, Han Xiaotong, Zhang Jianping, Huang Tingting, Li Zhefeng. Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery. 2025; 35(4), 1589-1597. Available from: doi:10.1007/s42823-025-00873-y
Kang Yingbo, Zhang Hai, Weng Yinglong, Han Xiaotong, Zhang Jianping, Huang Tingting and Li Zhefeng. "Modification of graphite-based composite bipolar plates by “nanoglue” strategy for vanadium redox flow battery" Carbon Letters 35, no.4 (2025) : 1589-1597.doi: 10.1007/s42823-025-00873-y
