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MnMgFe-LDHs/ZIF-8/B, N-WMCNTs nanocomposites for efficient electrochemical detection of nitrite and heavy metal ions

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2025, 35(5), pp.2287~2297
  • DOI : 10.1007/s42823-025-00922-6
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : February 14, 2025
  • Accepted : May 9, 2025
  • Published : December 11, 2025

Xue Du 1 Tong Han 1 Biao Jin 1 Long‑Yue Meng 1 Lian‑Hua Han 1

1Yanbian University

Accredited

ABSTRACT

Contamination of food with heavy metal ions and nitrites poses a serious threat to human health. Consequently, the development of fast and sensitive platforms for detecting these contaminants is urgently required. In this paper, a novel MnMgFe-LDHs/DC sensor is constructed based on a simple strategy, in which MnMgFe layered double hydroxide (LDHs) is used as a metal precursor, and a unique "island bridge" carbon network structure is generated by its pyrolysis with ZIF-8@B, N-WMCNTs. The electrical conductivity was enhanced, and a large electroactive surface area was provided for the MnMgFe-LDHs/DC. The electrochemical properties of Pb2+, Cd2+ and nitrite were investigated using this electrode as a working electrode. Under optimized conditions, the sensing platform exhibited a wide linear range with the Pb2+, Cd2+, and NO2− limits of detection of 46.16 nM, 59.25 nM, and 0.083 μM, respectively. Of particular note is that this sensing platform exhibits outstanding anti-interference capabilities. It can precisely and efficiently conduct the detection of nitrite and heavy metal ions in pickled foods.

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