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Transforming polyethylene foam into a hard carbon anode: a study on its structure and sodium storage behavior

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2026, 36(1), pp.365~378
  • DOI : 10.1007/s42823-025-00991-7
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : November 9, 2025
  • Accepted : December 8, 2025
  • Published : February 1, 2026

Moon Seungjae 1,  Kim Kitak 1,  Park Suah 1,  Yang Yongjun 1,  Kim Seung Gun 1,  Jin Heewon 1,  Kim Sang Eun 1,  Nam Seunghoon 1,  Dalsu Choi 1

1명지대학교

Accredited

ABSTRACT

In this study, we upcycled waste polyethylene (PE) foam into a hard carbon anode material for sodium-ion batteries (SIBs) via sulfonation and subsequent carbonization. Following an optimized sulfonation process (100 °C, 24 h), the sample carbonized at 800℃ (PE_C800) demonstrated the best performance, showing a high reversible capacity of 180 mAh·g− 1 at 0.1 C, excellent rate capability, and long-term cycling stability (93.3% retention after 100 cycles). Structural analysis revealed this sample possessed a hierarchical porous structure and an interlayer spacing (0.388 nm), suitable for Na+ insertion. Through cyclic voltammetry (CV) kinetic analysis and ex-situ Raman spectroscopy, the sodium storage was determined to follow an “adsorption-insertion model”, combining surface adsorption and interlayer insertion. This work presents a practical route for converting plastic waste into high performance energy storage materials.

Citation status

* References for papers published after 2025 are currently being built.

This paper was written with support from the National Research Foundation of Korea.