@article{ART003341980},
author={Ansari Sarfaraz and Choudhary Ram Bilash and Myrthong Batistalang},
title={Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode},
journal={Carbon Letters},
issn={1976-4251},
year={2026},
volume={36},
number={1},
pages={379-395},
doi={10.1007/s42823-025-00992-6}
TY - JOUR
AU - Ansari Sarfaraz
AU - Choudhary Ram Bilash
AU - Myrthong Batistalang
TI - Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode
JO - Carbon Letters
PY - 2026
VL - 36
IS - 1
PB - Korean Carbon Society
SP - 379
EP - 395
SN - 1976-4251
AB - An appropriate combination of electrode-electrolytes has the competence to augment the supercapacitive behaviour to a greater range of excellence. Following this, a binary polymeric composite PPy/o-CNTs (PC) has been synthesized via in-situ chemical oxidative polymerization of polypyrrole (PPy) in the presence of oxidized carbon nanotubes (o-CNTs) and its electrochemical performance has been evaluated in difference electrolytic environments viz. 1/2/3 M KCl and 1/2/3 M H2SO4. The composite PC elucidated the highest specific capacitance of 364.5 F g− 1 (at 100 mV s− 1) and 487.4 F g− 1 (at 1 A g− 1) in 3 M KCl and 729.9 F g− 1 (at 100 mV s− 1) and 559.7 F g− 1 (at 1 A g− 1) in 3 M H2SO4 respectively. The synthesized composite also showed significantly improved cyclic behaviour with capacitance retention up to 94.65% in 2 M KCl for 2000 GCD cycles. The improved electrochemical performance of PC could be attributed to the presence of o-CNT which not only provided a conductive network throughout the electrode materials to facilitate charge transfer kinetics but also provided a mechanically stable support thereby anchoring the polymeric chain to enhance the overall cyclic stability. Further, the lower value of solution resistance and charge transfer resistance also affirmed the ameliorated supercapacitive behaviour of PC.
KW - PPy Piranha solution CNTs Pseudocapacitance Solution resistance Electrolyte
DO - 10.1007/s42823-025-00992-6
ER -
Ansari Sarfaraz, Choudhary Ram Bilash and Myrthong Batistalang. (2026). Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode. Carbon Letters, 36(1), 379-395.
Ansari Sarfaraz, Choudhary Ram Bilash and Myrthong Batistalang. 2026, "Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode", Carbon Letters, vol.36, no.1 pp.379-395. Available from: doi:10.1007/s42823-025-00992-6
Ansari Sarfaraz, Choudhary Ram Bilash, Myrthong Batistalang "Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode" Carbon Letters 36.1 pp.379-395 (2026) : 379.
Ansari Sarfaraz, Choudhary Ram Bilash, Myrthong Batistalang. Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode. 2026; 36(1), 379-395. Available from: doi:10.1007/s42823-025-00992-6
Ansari Sarfaraz, Choudhary Ram Bilash and Myrthong Batistalang. "Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode" Carbon Letters 36, no.1 (2026) : 379-395.doi: 10.1007/s42823-025-00992-6
Ansari Sarfaraz; Choudhary Ram Bilash; Myrthong Batistalang. Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode. Carbon Letters, 36(1), 379-395. doi: 10.1007/s42823-025-00992-6
Ansari Sarfaraz; Choudhary Ram Bilash; Myrthong Batistalang. Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode. Carbon Letters. 2026; 36(1) 379-395. doi: 10.1007/s42823-025-00992-6
Ansari Sarfaraz, Choudhary Ram Bilash, Myrthong Batistalang. Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode. 2026; 36(1), 379-395. Available from: doi:10.1007/s42823-025-00992-6
Ansari Sarfaraz, Choudhary Ram Bilash and Myrthong Batistalang. "Electrochemically tuned oxidized carbon nanotubes reinforced polypyrrole matrix in varying electrolytic environment as supercapacitor electrode" Carbon Letters 36, no.1 (2026) : 379-395.doi: 10.1007/s42823-025-00992-6