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Puffing pretreatment for sorghum seed-derived porous carbon in optimized NiCo-LDH growth and superior supercapacitor performance

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2026, 36(1), pp.493~509
  • DOI : 10.1007/s42823-026-01026-5
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : September 4, 2025
  • Accepted : December 24, 2025
  • Published : February 1, 2026

Quan Ying 1 Li Yuanyuan 2 Zhang Yude 1 Zhang Qian 1 Wang Mengjia 3 Cheng Wenzhuo 2

1Collaborative Innovation Center of Coal Work Safety and Clean High Efficiency Utilization
2Henan Polytechnic University
3독립연구자

Accredited

ABSTRACT

Nickel-cobalt layered double hydroxide (NiCo-LDH) is a promising supercapacitor material, but its performance is limited by nanosheet stacking and poor conductivity. Incorporating a porous carbon support is an effective strategy to overcome these issues. Herein, porous carbon derived from both puffed and unpuffed sorghum seeds was synthesized at various pre-carbonization temperatures. The optimized carbon from puffed seeds (PH-R4A7), abundant in pyridinic-N and oxygen groups, facilitates the uniform growth of NiCo-LDH. The resulting NiCo-LDH/PH-R4A7 composite delivers a high specific capacitance of 807.2 C g− 1 at 1 A g− 1 and excellent capacitance retention (69.9% at 20 A g− 1), surpassing both pristine NiCo-LDH and its unpuffed counterpart (NiCo-LDH/PC-R4A7). Furthermore, an asymmetric supercapacitor (NiCo-LDH/PH-R4A7//PH-R6A7) achieves a high energy density of 85.1 Wh kg− 1 at a power density of 799.9 W kg− 1, along with outstanding cycling stability (88.4% capacitance retention after 10,000 cycles). This work demonstrates that puffing pretreatment is an important strategy for enhancing the structural and electrochemical properties of NiCo-LDH/porous carbon composites.

Citation status

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