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Synthesis and structure of (C6H5CH2NH3)2CuCl4 and(NH3C6H4C2H4C6H4NH3)CuCl4

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2004, 14(4), pp.135~139
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : April 28, 2004
  • Accepted : June 7, 2004

Ji Hyun Kim 1,  Seok Soon Kweon 1,  HYUN JUNEWON 1,  Young Duk Huh 1

1단국대학교

Accredited

ABSTRACT

The layered organic-inorganic hybrid compounds (C6H5CH2NH3)2CuCl4 and (NH3C6H4C2H4C6H4NH3)CuCl4 have been directly synthesized. From the X-ray diffraction data and the organic guest size, the orientation of the intercalated organic amine was determined. The inorganic sheets consist of CuCl42- layers of corner-sharing octahedra copper chloride. The protonated organic amine was intercalated into the CuCl42- layers with bilayer structure for (C6H5CH2NH3)2CuCl4 and monolayer structure for (NH3C6H4C2H4C6H4NH3)CuCl4.

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