@article{ART001051118},
author={안영수 and KANG SEUNG GU},
title={Structure and chemical durability of borosilicate glass-ceramics containing EAF dust},
journal={Journal of the Korean Crystal Growth and Crystal Technology},
issn={1225-1429},
year={2007},
volume={17},
number={2},
pages={82-89}
TY - JOUR
AU - 안영수
AU - KANG SEUNG GU
TI - Structure and chemical durability of borosilicate glass-ceramics containing EAF dust
JO - Journal of the Korean Crystal Growth and Crystal Technology
PY - 2007
VL - 17
IS - 2
PB - The Korea Association Of Crystal Growth, Inc.
SP - 82
EP - 89
SN - 1225-1429
AB - Glas-ceramics were fabricated by heat-treating a glas at 700oC/10 hr which was obtained by melting a glasfrit mixed with 40~80 wt% EAF dust at 1300oC/1 hr. Dependence of crystal phase and bonding state change upon aleaching procedure (TCLP) test data to investigate a chemical durability of the specimens. Increasing dust in a glass shiftedthe peak around 10 cm1 to the lower frequency which was composed of two vibration peaks for the nonbridging oxygenat 960 cm1 and the bridging oxygen at 1050~1060 cm1. Also, the B2O3 structure of boroxol ring changed to a tetrhedral-,trigonal- and di-borate with dust addition. The Fe-O peaks in the glas-ceramics were observed which is consitent witha glass-ceramics ater TCLP test so the chemical durability of the glass-ceramics is superior than that of glass. The leachingconcentration of Fe for the glass-ceramics containing EAF dust 80 wt% is 1/15 times lower than that of glas. The Znleaching concentration for the glass-ceramics containing dust < 70 wt% was higher than that of glass but its trend wasreversed for the specimen of dust content > 80 wt% which could be concluded as corelated with occurence of wilemitephase.Key words EAF dust, Borate glass, Glas-ceramics, Heavy metal, Stabilization, Chemical durability, Spinel, Willemite,FT-IREAF dust. ... ..... ... ... .. . ... ........ ...†
KW - EAF dust;Borate glass;Glass-ceramics;Heavy metal;Stabilization;Chemical durability;Spinel;Willemite;
FT-IR
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안영수 and KANG SEUNG GU. (2007). Structure and chemical durability of borosilicate glass-ceramics containing EAF dust. Journal of the Korean Crystal Growth and Crystal Technology, 17(2), 82-89.
안영수 and KANG SEUNG GU. 2007, "Structure and chemical durability of borosilicate glass-ceramics containing EAF dust", Journal of the Korean Crystal Growth and Crystal Technology, vol.17, no.2 pp.82-89.
안영수, KANG SEUNG GU "Structure and chemical durability of borosilicate glass-ceramics containing EAF dust" Journal of the Korean Crystal Growth and Crystal Technology 17.2 pp.82-89 (2007) : 82.
안영수, KANG SEUNG GU. Structure and chemical durability of borosilicate glass-ceramics containing EAF dust. 2007; 17(2), 82-89.
안영수 and KANG SEUNG GU. "Structure and chemical durability of borosilicate glass-ceramics containing EAF dust" Journal of the Korean Crystal Growth and Crystal Technology 17, no.2 (2007) : 82-89.
안영수; KANG SEUNG GU. Structure and chemical durability of borosilicate glass-ceramics containing EAF dust. Journal of the Korean Crystal Growth and Crystal Technology, 17(2), 82-89.
안영수; KANG SEUNG GU. Structure and chemical durability of borosilicate glass-ceramics containing EAF dust. Journal of the Korean Crystal Growth and Crystal Technology. 2007; 17(2) 82-89.
안영수, KANG SEUNG GU. Structure and chemical durability of borosilicate glass-ceramics containing EAF dust. 2007; 17(2), 82-89.
안영수 and KANG SEUNG GU. "Structure and chemical durability of borosilicate glass-ceramics containing EAF dust" Journal of the Korean Crystal Growth and Crystal Technology 17, no.2 (2007) : 82-89.