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Nano inclusions in sapphire samples from Sri Lanka

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2009, 19(2), pp.84-89
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering

K. Jaijong 1 Kim, Young-chool 2 Choi, Hyun-min 2 방신영 1 Bonggeun Choi 1 Kwang Bo Shim 1 P. Wathanakul 3

1한양대학교
2㈜한미보석감정원
3Kasetsart University

Accredited

ABSTRACT

The turbid/translucent, near colorless (milky) metamorphic sapphire samples from Sri Lanka have been characterized after the heat treatment in N2 at 1650 oC. As-received sapphire specimens became bluish-colored and exhibited more clarity after the heat treatment. It was found that the color change at inclusions zoning region is attributed by the dissolution. As received samples contain the micro/nano inclusions such as rutile (TiO2), ilmenite (FeTiO3), spinel (MgAl2O4)/ulvospinel (Fe2TiO4) and apatite (Ca5(PO4)3), which were dissolved by the heat treatment and form the blue color through Fe2+/Ti4+ charge transferring. The microstructures become different because as the dissolution of apatite (Ca5(PO4)3(OH,F,Cl)) in alumino silicates (Al2SiO5) occurred, resulting in morphological change with the appearance of (Ca, Mg, Al) silicate on the surface. Both as-received and heat treated samples showed the rhombohedral crystal structure of Al2O3.

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