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Effect of process conditions on crystal structure of Al PEO coating. II. Bipolar and electrolyte

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2014, 24(2), pp.65-69
  • DOI : 10.6111/JKCGCT.2014.24.2.065
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering

Bae-Yeon Kim 1 함재호 1 DeukYong Lee ORD ID 2 Yongnam Kim 3 전민석 3 Kim, KI-Youn 1 Ji-Won Choi ORD ID 4 Sung Youp Kim 5 Kwang Youp Kim 5

1인천대학교
2대림대학교
3한국산업기술시험원
4한국과학기술연구원
5MST Technology

Accredited

ABSTRACT

Crystallographic phases of Plasma electrolytic oxidized Al alloy, A1100, A5052, A6061, A6063, A7075, wereinvestigated. Two types of electrolyte Na2Si2O3 and Na2P2O7 were also compared. Bipolar pulse, 2000 μsec with 400 μsec +420 V impulse and 300 μsec − impulse were applied for 20 min. α-Alumina, γ-alumina, η-alumina, Al4.95Si1.05O9.52, and(Al0.9Cr0.1)2O3 were mainly observed. Si, component of electrolyte, were moved into the PEO layer by bipolar pulse. Glassyphase was also observed at the surface of Na2Si2O3 electrolyte treated PEO layer, and increased with the Mg content of Alalloy. It is concluded that at first glassy phase was formed by the micro plasma, and the high temperature of plasma turnsglassy phase to several crystalline phases. And we could expect that many other crystalline phase could be formed by PEOprocess.

Citation status

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