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Upconversion luminescence from poly-crystalline Yb 3+ , Er 3+ co-doped NaGd(MoO4)2 by simple solid state method

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2016, 26(4), pp.159-163
  • DOI : 10.6111/JKCGCT.2016.26.4.159
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Published : August 31, 2016

Suk Hyun Kang 1 Hyo Sang Kang 1 Hee Ae Lee 1 Kwang Bo Shim 1

1한양대학교

Accredited

ABSTRACT

Up-conversion (UC) luminescence properties of polycrystalline Er 3+ /Yb 3+ doped NaGd(MoO4)2 phosphors synthesized by a simple solid-state reaction method were investigated in detail. Used to 980 nm excitation (InfraRed area), Er 3+ /Yb 3+ co-doped NaGd(MoO4)2 exhibited very weak red emissions near 650 and 670 nm, and very strong green UC emissions at 540 and 550 nm corresponding to the infra 4f transitions of Er 3+ ( 4 F9/2, 2 H11/2, 4 S3/2)→Er 3+ ( 4 I15/2). The optimum doping concentration of Er 3+ , Yb 3+ for highest emission intensity was determined by XRD and PL analysis. The Er 3+ /Yb 3+ (10.0/10.0 mol%) co-doped NaGd(MoO4)2 phosphor sample exhibited very strong shiny green emission. A possible UC mechanism for Er 3+ /Yb 3+ co-doped NaGd(MoO4)2 depending on the pump power dependence was discussed.

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