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Synthesis of zinc oxide nanoparticles via aqueous solution routes

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2016, 26(5), pp.175-180
  • DOI : 10.6111/JKCGCT.2016.26.5.175
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : September 27, 2016
  • Accepted : October 7, 2016
  • Published : October 31, 2016

Jin Heui Koo 1 Jun Seok Yang 1 Soo Jin Cho 1 BYEONG WOO LEE 1

1한국해양대학교

Accredited

ABSTRACT

ZnO nanoparticles were synthesized by aqueous preparation routes of a precipitation and a hydrothermal process. In the processes, the powders were formed by mixing aqueous solutions of Zn-nitrate hexahydrate (Zn(NO3)2 · 6H2O) with NaOH aqueous solution under controlled reaction conditions such as Zn precursor concentration, reaction pH and temperature. Single ZnO phase has been obtained under low Zn precursor concentration, high reaction pH and high temperature. The synthesized particles exhibited flakes (plates), multipods or rods morphologies and the crystallite sizes and shapes would be efficiently controllable by changing the processing parameters. The hydrothermal method showed advantageous features over the precipitation process, allowing the precipitates of single ZnO phase with higher crystallinity at relatively low temperatures below 100 o C under a wider pH range for the Zn precursor concentration of 0.1~1 M.

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