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Synthesis of calcium phosphates from abalone shells via precipitation

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2020, 30(4), pp.143-149
  • DOI : 10.6111/JKCGCT.2020.30.4.143
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : July 20, 2020
  • Accepted : August 3, 2020
  • Published : August 31, 2020

Sung Wook Moon 1 BYEONG WOO LEE 1

1한국해양대학교

Accredited

ABSTRACT

Calcium phosphates recognized as important bio-materials have been successfully synthesized by simple precipitationusing waste abalone shells, which are rich mineral sources of calcium. Calcium hydroxide (Ca(OH)2) originated from abalone shells was used as calcium source (precursor) for the preparation. Synthesis of calcium phosphates was performed by reacting calcium hydroxide with phosphoric acid (H3PO4) in aqueous solution. The initial precursor Ca/P ratios were adjusted to 1.50, 1.59 and 1.67, and the effect of the composition and the heat treatment on the synthesized powders and sintered bodies was investigated. The phases of the sintered ceramics prepared at 1150°C were hydroxyapatite (HAp), β-tricalcium phosphate(β-TCP), and biphasic phosphate (HAp with β-TCP)), which were determined by the initial precursor Ca/P ratios. The results demonstrate the possibility for the synthesis of high value-added calcium phosphates from economical starting materials with low cost and high availability.

Citation status

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This paper was written with support from the National Research Foundation of Korea.