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Evidence of spin-phonon coupling in La2NiMnO6 double perovskite

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2021, 31(3), pp.112~115
  • DOI : 10.6111/JKCGCT.2021.31.3.112
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : May 6, 2021
  • Accepted : May 26, 2021
  • Published : June 30, 2021

Mohammad Nasir 1,  Ateeq Ahmed 2,  Hee Jung Park 3,  Somaditya Sen 4

1단국대학교 신소재공학과
2조선대학교
3단국대학교
4Indian Institute of Technology Indore

Accredited

ABSTRACT

Herein, a correlation between B-site cation order and spin-phonon coupling in La2NiMnO6 double perovskite hasbeen investigated. Raman spectra of La2NiMnO6 double perovskite annealed at 950 and 1400°C have been measured in the140-598 K range. A substantial softening of the phonon modes has been observed below the Curie temperature, whichemphasized the presence of the spin-phonon coupling in the system. The spin-phonon coupling was found to be stronger inrelatively more ordered La2NiMnO6 double perovskite. Thus, the magnitude of spin-phonon coupling was influenced by theNi/Mn cation order.

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This paper was written with support from the National Research Foundation of Korea.