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Crystal structure and microstructure of Z-type hexaferrite (Ba, La)Co2Fe24O41 by molten salt synthesis

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2021, 31(5), pp.197-202
  • DOI : 10.6111/JKCGCT.2021.31.5.197
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : September 2, 2021
  • Accepted : September 30, 2021
  • Published : October 31, 2021

Do Hyeok Lee 1 Chae-Yeon Kwon 2 Kyoung-Seok Moon 3

1경상대학교 나노·신소재공학부 세라믹공학과
2한국재료연구원 표면재료연구본부
3경상대학교

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ABSTRACT

Synthesis of Z-type hexaferrite Ba3Co2Fe24O41 (Ba3Z) and Ba1.5La1.5Co2Fe24O41 (Ba1.5La1.5Z) powders were tried usingmolten salt synthesis after primary calcination. Ba3Z calcined at 1000℃ was formed with both M-type and Y-type hexaferrite,and then Z-type was obtained when sintered with molten salt at 1150°C and 1200°C. In the case of Ba1.5La1.5Z calcined at1000°C, however, M-type hexaferrite, CoFe2O4 (Spinel phase), and LaFeO3 were synthesized. As a result, Z-type hexaferritewas not synthesized after sintering with molten salt. In addition, the aspect ratio of the particles decreased as the sinteringtemperature increased with molten salt synthesis. To obtain a single-phase Ba1.5La1.5Z with a high aspect ratio, it is expectedthe raw materials have to calcine below the temperature of a spinel phase formation before sintering with molten salt.

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