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A study on the brownish ring of quartz glass crucible for silicon single crystal ingot

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2022, 32(3), pp.115-120
  • DOI : 10.6111/JKCGCT.2022.32.3.115
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : June 2, 2022
  • Accepted : June 10, 2022
  • Published : June 30, 2022

Yoon Sung Jung 1 Jae Ho Choi 1 Kyung Won Min 2 Young Min Byeon 2 Won Bin Im 2 Sung-Hun Noh 3 Nam-Hun Kang 3 Kim Hyeong Jun 4

1한양대학교 신소재공학과
2한양대학교
3(주)SGC
4한국세라믹기술원

Accredited

ABSTRACT

A brown ring (hereinafter referred to as BR) on the inner surface of a quartz glass crucible used in the manufacturing process of a silicon ingot for semiconductor wafers was studied. BR is 20~30 µm in size and has an asymmetric brown ring shape. The size and distribution of BR were different depending on the crucible location, and the size and distribution of BR were the largest and most abundant in the round part with the highest crucible temperature during Si ingot growth. BR contains cristobalite, which has a higher coefficient of thermal expansion than quartz glass, so it is considered that surface cracks appear. The color development of BR and pin holes are presumed to be due to oxygen vacancies.

Citation status

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