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Fundamental studies on thermosolutal convection in mercurous bromide (Hg2Br2) physical vapor transport processes

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2023, 33(3), pp.110-115
  • DOI : 10.6111/JKCGCT.2023.33.3.110
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : May 12, 2023
  • Accepted : June 9, 2023
  • Published : June 30, 2023

Geug Tae Kim 1 Moo Hyun Kwon 2

1한남대학교
2우석대학교

Accredited

ABSTRACT

During the Hg₂Br₂ physical vapor transport process, with increasing the partial pressure of component B, PB from 40 Torr to 200 Torr, a unicellular convective flow structures move from the crystal growth region to the center region in the vapor phase. The boundary layer flow is dominant for PB = 40 Torr, and the core region flow is dominant for PB = 200 Torr. The flow in the vapor phase shows a three-dimensional convective flow structure with a single cell (unicellular) for PB = 40 Torr and 200 Torr, exhibits an asymmetrical flow with respect to the x, y central axis under the horizontally oriented configuration with an aspect ratio (length-to-width) of 3 and linear conducting walls. The critical temperature difference between the source and crystal region is about 30 K. The total molar flux of Hg₂Br₂ increases with the temperature difference until the total molar flux reaches the critical value. At the critical total molar flux, the total molar flux abruptly decreases.

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