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Development of novel oxyfluoride glasses and glass ceramics for photoluminescence material by a containerless processing

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2023, 33(5), pp.181-186
  • DOI : 10.6111/JKCGCT.2023.33.5.181
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : August 25, 2023
  • Accepted : September 11, 2023
  • Published : October 31, 2023

Hyerin Jo 1 Minsung Hwang 1 Youngjin Lee 1 Jaeyeop Chung 1

1한국세라믹기술원

Accredited

ABSTRACT

In this study, novel Eu₂O₃-BaF₂-La₂O₃-B₂O₃ oxyfluoride glasses and glass ceramics were developed by a containerless processing. Differential thermal analysis (DTA) analysis was performed to analyze the thermophysicalproperties of oxyfluoride glasses doped with Eu₂O₃, and photoluminescence (PL) characteristics were analyzed to evaluate the luminous efficiency depending on the degree of crystallinity. The glass transition temperature decreased with increasing BaF₂ concentration since BaF₂ acts as a network modifier in this glass system. In addition, thermal stability which can beestimated by the difference between the glass transition temperature and the onset temperature of the crystallization decreased with increasing BaF₂ contents. The peak related to the BaF₂ crystal was confirmed after the crystallization by X-ray Diffraction (XRD) analysis. Photoluminescence intensity increased after the crystallization which indicates that the Eu3+ ions are sited in BaF₂ crystal. La 3d5/2 x-ray photoelectron spectroscopy (XPS) and F1s XPS spectra were analyzed to precisely understand the behavior of the fluorine ion in the glass structure. Fluorine tends to bond with the network modifying cations such as La³+ and Ba²+ ions and after the crystallization the La-F bonds decreased because F- ions used to form BaF₂ crystals.

Citation status

* References for papers published after 2023 are currently being built.