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Synthesis of Fe-doped β-Ni(OH)₂ microcrystals and their oxygen evolution reactions

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2023, 33(5), pp.196-201
  • DOI : 10.6111/JKCGCT.2023.33.5.196
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : October 21, 2023
  • Accepted : October 24, 2023
  • Published : October 31, 2023

Je Hong Park 1 Si beom Yu 1 Seungwon Jeong 1 Byeong Jun Kim 1 Kangmin Kim 2 Jeong-ho Ryu 1

1한국교통대학교
2한국생산기술연구원

Accredited

ABSTRACT

In order to improve the efficiency of the water splitting system for hydrogen energy production, the high overvoltage in the electrochemical reaction caused by the catalyst in the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) must be reduced. Among them, transition metal-based compounds (hydroxide, sulfide, etc.) are attracting attention as catalyst materials to replace currently used precious metals such as platinum. In this study, Ni foam, an inexpensive metal porous material, was used as a support and β-Ni(OH)₂ microcrystals were synthesized through a hydrothermal synthesis process. In addition, changes in the crystal morphology, crystal structure, and water splitting characteristics of β-Ni(OH)₂ microcrystals synthesized by doping Fe to improve electrochemical properties were observed, and applicability as a catalyst in a commercial water electrolysis system was examined.

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This paper was written with support from the National Research Foundation of Korea.