@article{ART003246193},
author={Young Ji Park and Yeon-Bin Choi and Sang Hyo Jeong and Kang Taewook and Byungseo Bae and Sun Woog Kim},
title={Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors},
journal={Journal of the Korean Crystal Growth and Crystal Technology},
issn={1225-1429},
year={2025},
volume={35},
number={3},
pages={87-94},
doi={10.6111/JKCGCT.2025.35.3.087}
TY - JOUR
AU - Young Ji Park
AU - Yeon-Bin Choi
AU - Sang Hyo Jeong
AU - Kang Taewook
AU - Byungseo Bae
AU - Sun Woog Kim
TI - Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors
JO - Journal of the Korean Crystal Growth and Crystal Technology
PY - 2025
VL - 35
IS - 3
PB - The Korea Association Of Crystal Growth, Inc.
SP - 87
EP - 94
SN - 1225-1429
AB - Single-phase α-,β-, and γ-MnO₂ nanoparticles with high crystallinity were successfully synthesized by a hydrothermal process using different Mn precursors, such as Mn(OAc)₂, MnSO₄, MnCl₂, and Mn(NO₃)₂. The crystal structure and morphology of the MnO₂ particles could be effectively controlled by changing the Mn source. The use of Mn(OAc)₂ and MnSO₄ as precursors resulted in rod-shaped α- and β-MnO₂ particles, whereas MnCl₂, and Mn(NO₃)₂ yielded aggregated angular nanoparticles of γ-MnO₂. X-ray photoelectron spectroscopic analysis revealed that β-MnO₂ had a high ratio of Mn4+ and Olatt on the particle surface, whereas α- and γ-MnO₂ sample had a lower valence state of Mn, such as Mn3+ and Mn2+, on the surface, and the ratio of Olatt was also relatively low.
KW - α-;β-;and γ-MnO₂;Acidity;Hydrothermal process;Particle morphology
DO - 10.6111/JKCGCT.2025.35.3.087
ER -
Young Ji Park, Yeon-Bin Choi, Sang Hyo Jeong, Kang Taewook, Byungseo Bae and Sun Woog Kim. (2025). Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors. Journal of the Korean Crystal Growth and Crystal Technology, 35(3), 87-94.
Young Ji Park, Yeon-Bin Choi, Sang Hyo Jeong, Kang Taewook, Byungseo Bae and Sun Woog Kim. 2025, "Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors", Journal of the Korean Crystal Growth and Crystal Technology, vol.35, no.3 pp.87-94. Available from: doi:10.6111/JKCGCT.2025.35.3.087
Young Ji Park, Yeon-Bin Choi, Sang Hyo Jeong, Kang Taewook, Byungseo Bae, Sun Woog Kim "Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors" Journal of the Korean Crystal Growth and Crystal Technology 35.3 pp.87-94 (2025) : 87.
Young Ji Park, Yeon-Bin Choi, Sang Hyo Jeong, Kang Taewook, Byungseo Bae, Sun Woog Kim. Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors. 2025; 35(3), 87-94. Available from: doi:10.6111/JKCGCT.2025.35.3.087
Young Ji Park, Yeon-Bin Choi, Sang Hyo Jeong, Kang Taewook, Byungseo Bae and Sun Woog Kim. "Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors" Journal of the Korean Crystal Growth and Crystal Technology 35, no.3 (2025) : 87-94.doi: 10.6111/JKCGCT.2025.35.3.087
Young Ji Park; Yeon-Bin Choi; Sang Hyo Jeong; Kang Taewook; Byungseo Bae; Sun Woog Kim. Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors. Journal of the Korean Crystal Growth and Crystal Technology, 35(3), 87-94. doi: 10.6111/JKCGCT.2025.35.3.087
Young Ji Park; Yeon-Bin Choi; Sang Hyo Jeong; Kang Taewook; Byungseo Bae; Sun Woog Kim. Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors. Journal of the Korean Crystal Growth and Crystal Technology. 2025; 35(3) 87-94. doi: 10.6111/JKCGCT.2025.35.3.087
Young Ji Park, Yeon-Bin Choi, Sang Hyo Jeong, Kang Taewook, Byungseo Bae, Sun Woog Kim. Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors. 2025; 35(3), 87-94. Available from: doi:10.6111/JKCGCT.2025.35.3.087
Young Ji Park, Yeon-Bin Choi, Sang Hyo Jeong, Kang Taewook, Byungseo Bae and Sun Woog Kim. "Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors" Journal of the Korean Crystal Growth and Crystal Technology 35, no.3 (2025) : 87-94.doi: 10.6111/JKCGCT.2025.35.3.087