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Crystal structure control of nanosized MnO₂ particles synthesized by a hydrothermal process using different Mn precursors

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2025, 35(3), pp.87~94
  • DOI : 10.6111/JKCGCT.2025.35.3.087
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : July 30, 2025
  • Accepted : August 20, 2025
  • Published : September 30, 2025

Young Ji Park 1 Yeon-Bin Choi 2 Sang Hyo Jeong 3 Kang Taewook 3 Byungseo Bae 2 Sun Woog Kim ORD ID 3

1경상대학교
2영월산업진흥원
3한국세라믹기술원

Accredited

ABSTRACT

Single-phase α-,β-, and γ-MnO₂ nanoparticles with high crystallinity were successfully synthesized by a hydrothermal process using different Mn precursors, such as Mn(OAc)₂, MnSO₄, MnCl₂, and Mn(NO₃)₂. The crystal structure and morphology of the MnO₂ particles could be effectively controlled by changing the Mn source. The use of Mn(OAc)₂ and MnSO₄ as precursors resulted in rod-shaped α- and β-MnO₂ particles, whereas MnCl₂, and Mn(NO₃)₂ yielded aggregated angular nanoparticles of γ-MnO₂. X-ray photoelectron spectroscopic analysis revealed that β-MnO₂ had a high ratio of Mn4+ and Olatt on the particle surface, whereas α- and γ-MnO₂ sample had a lower valence state of Mn, such as Mn3+ and Mn2+, on the surface, and the ratio of Olatt was also relatively low.

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