In this research, the distribution of Platinum Group Elements (PGEs) at roadside dust in Daejeon, Korea was examined using an ICP-MS (Inductively Coupled Plasma-Mass Spectrometry) technique. For the quality assurance of the determination, method validation based on its accuracy and precision was conducted using SRM (Standard Reference Material). It was found that the relative errors of Pt, Pd, and Rh against each SRM value were -0.7%, -10.0%, and -20.4%, respectively, while relative standard deviations for three elements were less than 10%. The concentrations of Pt, Pd and Rh in roadside dust averaged as 17.4±9.2 μg/kg, 283.6±20.5 μg/kg, and 7.3±2.8 μg/kg, respectively. The concentrations of Pt and Rh have significantly higher distribution patterns in the dust at roadside and underground parking lot than those in soil of the background or other urban area. The correlation analysis between concentrations of PGEs in roadside dust indicates that the distribution of Pt and Rh concentration were strongly affected by automobile sources.