@article{ART002964078},
author={Zhang Chunhong and Xu Zice and Sui Wenbo and Zang Junbo and Ao Yuhui and Wang Lu and Shang Lei},
title={Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites},
journal={Carbon Letters},
issn={1976-4251},
year={2023},
volume={33},
number={2},
pages={501-516},
doi={10.1007/s42823-022-00440-9}
TY - JOUR
AU - Zhang Chunhong
AU - Xu Zice
AU - Sui Wenbo
AU - Zang Junbo
AU - Ao Yuhui
AU - Wang Lu
AU - Shang Lei
TI - Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites
JO - Carbon Letters
PY - 2023
VL - 33
IS - 2
PB - Korean Carbon Society
SP - 501
EP - 516
SN - 1976-4251
AB - Epoxy resin (EP) is a thermosetting resin with excellent properties, but its application is limited due to its high brittleness and poor flame retardancy. Therefore, to solve this problem, a dispersion system of imidazole-containing ionic liquid ([Dmim]Es) and graphene in epoxy resin is designed based on the π–π stacking effect between imidazole and graphite layers. The study on the thermal and flame-retardant properties of the composites show that the modified [Dmim]Es–graphene nanosheets improved the flame retardancy, smoke suppression and thermal stability of epoxy resin. With the addition of 5wt% [Dmim]Es and 1% Gra, the exothermic rate (HRR) and total exothermic (THR) of the composites decrease by 35% and 30.2% compared with the untreated epoxy cross-linking, respectively. The limiting oxygen index reaches 33.4%, the UL-94 test rating reaches V-0. The characterization of mechanical properties shows that the tensile properties and impact properties increased by 13% and 30%, respectively. Through SEM observation, the addition of [Dmim]Es improves the dispersion of graphene in the EP collective and changes the mechanical fracture behavior. The results show that ionic liquid [Dmim]Es-modified graphene nanosheets are well dispersed in the matrix, which not only improves the mechanical properties of epoxy resin (EP), but also has a synergistic effect on flame retardancy. This work provides novel flame-retardant and graphene dispersion methods that broaden the range of applications of epoxy resins.
KW - Ionic liquid Flame retardant Graphene Nanocomposite
DO - 10.1007/s42823-022-00440-9
ER -
Zhang Chunhong, Xu Zice, Sui Wenbo, Zang Junbo, Ao Yuhui, Wang Lu and Shang Lei. (2023). Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites. Carbon Letters, 33(2), 501-516.
Zhang Chunhong, Xu Zice, Sui Wenbo, Zang Junbo, Ao Yuhui, Wang Lu and Shang Lei. 2023, "Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites", Carbon Letters, vol.33, no.2 pp.501-516. Available from: doi:10.1007/s42823-022-00440-9
Zhang Chunhong, Xu Zice, Sui Wenbo, Zang Junbo, Ao Yuhui, Wang Lu, Shang Lei "Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites" Carbon Letters 33.2 pp.501-516 (2023) : 501.
Zhang Chunhong, Xu Zice, Sui Wenbo, Zang Junbo, Ao Yuhui, Wang Lu, Shang Lei. Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites. 2023; 33(2), 501-516. Available from: doi:10.1007/s42823-022-00440-9
Zhang Chunhong, Xu Zice, Sui Wenbo, Zang Junbo, Ao Yuhui, Wang Lu and Shang Lei. "Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites" Carbon Letters 33, no.2 (2023) : 501-516.doi: 10.1007/s42823-022-00440-9
Zhang Chunhong; Xu Zice; Sui Wenbo; Zang Junbo; Ao Yuhui; Wang Lu; Shang Lei. Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites. Carbon Letters, 33(2), 501-516. doi: 10.1007/s42823-022-00440-9
Zhang Chunhong; Xu Zice; Sui Wenbo; Zang Junbo; Ao Yuhui; Wang Lu; Shang Lei. Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites. Carbon Letters. 2023; 33(2) 501-516. doi: 10.1007/s42823-022-00440-9
Zhang Chunhong, Xu Zice, Sui Wenbo, Zang Junbo, Ao Yuhui, Wang Lu, Shang Lei. Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites. 2023; 33(2), 501-516. Available from: doi:10.1007/s42823-022-00440-9
Zhang Chunhong, Xu Zice, Sui Wenbo, Zang Junbo, Ao Yuhui, Wang Lu and Shang Lei. "Synergistic effect of novel ionic liquid/graphene complex on the flame retardancy of epoxy nanocomposites" Carbon Letters 33, no.2 (2023) : 501-516.doi: 10.1007/s42823-022-00440-9