Porous polyhedral carbon matrix for high-performance Li/Na/K-ion battery anodes

Ganesan Vinoth; Lee Young-Han; Jung Heechul; Park Cheol-Min

doi:10.1007/s42823-023-00559-3

Porous polyhedral carbon matrix for high-performance Li/Na/K-ion battery anodes

Carbon Letters
Abbr : Carbon Lett.
2023, 33(7), pp.2189~2198
DOI : 10.1007/s42823-023-00559-3
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : May 9, 2023
Accepted : June 14, 2023
Published : December 1, 2023

Ganesan Vinoth ¹, Lee Young-Han ¹, Jung Heechul ², Park Cheol-Min ¹

¹School of Materials Science and Engineering, Kumoh National Institute of Technology, Gumi, Gyeongbuk, 39177, Republic of Korea
²Department of Energy and Mineral Resources Engineering, Dong-A University, Saha-gu, Busan, 49315, Republic of Korea

Accredited

ABSTRACT

A carbon matrix for high-capacity Li/Na/K-alloy-based anode materials is required because it can effectively accommodate the variation in the volume of Li/Na/K-alloy-based anode materials during cycling. Herein, a nanostructured porous polyhedral carbon (PPC) was synthesized via a simple two-step method consisting of carbonization and selective acid etching, and their electrochemical Li/Na/K-ion storage performance was investigated. The highly uniform PPC, with an average particle size of 800 nm, possesses a porous structure and large specific surface area of 258.82 cm2 g–1. As anodes for Li/Na/K-ion batteries (LIBs/NIBs/KIBs), the PPC matrix exhibited large initial reversible capacity, fast rate capability (LIB: ~ 320 mAh g–1 at 3C; NIB: ~ 140 mAh g–1 at 2C; KIB: ~ 110 mAh g–1 at 2C), better cyclic performance (LIB: ~ 550 mAh g–1; NIB: ~ 210 mAh g–1; KIB: ~ 190 mAh g–1 at 0.2C over 100 cycles), high ionic diffusivity, and excellent structural robustness upon cycling, which demonstrates that the PPC matrix can be highly used as a carbon matrix for high-capacity alloy-based anode materials for LIBs/NIBs/KIBs.

KEYWORDS

Li/Na/K-ion batteries Porous polyhedral carbon Carbon-based matrices Carbon-based anodes Electrochemistry

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[journal] Armand M / 2008 / Building better batteries / Nature 451 : 652~657

[journal] Dunn B / 2011 / Electrical energy storage for the grid : a battery of choices / Science 334(6058) : 928~935

[journal] Slater MD / 2012 / Sodium-ion batteries / Adv Funct Mater 23(8) : 947~958

[journal] Kubota K / 2018 / Towards K-ion and Na-ion batteries as “beyond Li-ion” / Chem Rec 18(4) : 459~479

[journal] Stevens DA / 2001 / The mechanisms of lithium and sodium insertion in carbon materials / J Electrochem Soc 148 : A803~A811

[journal] Li Y / 2019 / Intercalation chemistry of graphite : alkali metal ions and beyond / Chem Soc Rev 48(17) : 4655~4687

[journal] Zhao LF / 2021 / Hard carbon anodes : fundamental understanding and commercial perspectives for Na-ion batteries beyond Li-ion and K-ion counterparts / Adv Energy Mater 11(1) : 2002704~

[journal] Lee SW / 2010 / High-power lithium batteries from functionalized carbon-nanotube electrodes / Nat Nanotechnol 5 : 531~537

[journal] Zhao C / 2015 / Reduction of graphene oxide in Li-ion batteries / J Mater Chem A 3(36) : 18360~18364

[journal] Cao YL / 2012 / Sodium ion insertion in hollow carbon nanowires for battery applications / Nano Lett 12(7) : 3783~3787

[journal] Wen Y / 2014 / Expanded graphite as superior anode for sodium-ion batteries / Nat Commun 5 : 4033~

[journal] Li W / 2017 / Carbon nanofiber-based nanostructures for lithium-ion and sodium-ion batteries / J Mater Chem A 5(27) : 13882~13906

[journal] Share K / 2016 / Mechanism of potassium ion intercalation staging in few layered graphene from in situ Raman spectroscopy / Nanoscale 8(36) : 16345~16439

[journal] Wang Y / 2018 / Hyper porous sponge interconnected by hierarchical carbon nanotubes as a high-performance potassium-ion battery anode / Adv Mater 30(32) : 1802074~

[journal] Liu Y / 2018 / Nitrogen-doped bamboo-like carbon nanotubes as anode material for high performance potassium ion batteries / J Mater Chem A 6(31) : 15162~15169

[journal] Park CM / 2010 / Li-alloy based anode materials for Li secondary batteries / Chem Soc Rev 39(8) : 3115~3141

[journal] Chevrier VL / 2011 / Challenges for Na-ion negative electrodes / J Electrochem Soc 158 : A1011~A1014

[journal] Obrovac MN / 2014 / Alloy negative electrodes for Li–ion batteries / Chem Rev 114(23) : 11444~11502

[journal] Sultana I / 2016 / Tin-based composite anodes for potassium–ion batteries / Chem Commun 52(59) : 9279~9282

[journal] Zheng J / 2019 / Extremely stable antimony–carbon composite anodes for potassium–ion batteries / Energy Environ Sci 12(2) : 615~623

[journal] Chen KT / 2020 / Bi–Sb nanocrystals embedded in phosphorus as high-performance potassium ion battery electrodes / ACS Nano 14(9) : 11648~11661

[journal] Zhang C / 2017 / Porous carbons derived from hypercrosslinked porous polymers for gas adsorption and energy storage / Carbon 114 : 608~618

[journal] Matos I / 2017 / Porous carbon : a versatile material for catalysis / Catal Today 285(1) : 194~203

[journal] Hou M / 2021 / Three-dimensional porous ultrathin carbon networks reinforced PBAs-derived electrocatalysts for efficient oxygen evolution / Chem Eng J 419 : 129575~

[journal] Oh Yun Ji / 2021 / Facile preparation of ZnO quantum dots@porous carbon composites through direct carbonization of metal–organic complex for high-performance lithium ion batteries / Carbon Letters / 한국탄소학회 31(2) : 323~329

[journal] Shaker Majid / 2021 / A criterion combined of bulk and surface lithium storage to predict the capacity of porous carbon lithium-ion battery anodes: lithium-ion battery anode capacity prediction / Carbon Letters / 한국탄소학회 31(5) : 985~990

[journal] Li D / 2018 / Facile fabrication of nitrogen-doped porous carbon as superior anode material for potassium-ion batteries / Adv Energy Mater 8(34) : 1802386~

[journal] Liu H / 2017 / Porous carbon composites for next generation rechargeable lithium batteries / Adv Energy Mater 7(24) : 1700283~

[journal] Yu L / 2013 / Hydrothermal nanocasting : Synthesis of hierarchically porous carbon monoliths and their application in lithium–sulfur batteries / Carbon 61 : 245~253

[journal] Jung DS / 2014 / Hierarchical porous carbon by ultrasonic spray pyrolysis yields stable cycling in lithium–sulfur battery / Nano Lett 14(8) : 4418~4425

[journal] Chen Liang / 2023 / Dual-template synthesis of interconnected 3D hollow N-doped carbon network for electrochemical application / Carbon Letters / 한국탄소학회 33(2) : 409~418

[journal] Wu Lili / 2022 / Study of the preparation and electrochemical performance of porous carbon derived from hypercrosslinked polymers / Carbon Letters / 한국탄소학회 32(3) : 849~862

[journal] Wang E / 2019 / Synthesis strategies and structural design of porous carbon-incorporated anodes for sodium-ion batteries / Small Methods 4(6) : 1900163~

[journal] Lee Seung Eun / 2021 / Effect of crystallinity and particle size on coke-based anode for lithium ion batteries / Carbon Letters / 한국탄소학회 31(5) : 911~920

[journal] Jo Kyoung-Il / 2022 / Gamma-ray irradiated graphene nanosheets/polydopamine hybrids as a superior anode material for lithium-ion batteries / Carbon Letters / 한국탄소학회 32(1) : 305~312

[journal] Wang D / 2019 / In situ double-template fabrication of boron-doped 3D hierarchical porous carbon network as anode materials for Li-and Na-ion batteries / Appl Surf Sci 464 : 422~428

[journal] Yu H / 2019 / Porous carbon derived from metal–organic framework@graphene quantum dots as electrode materials for supercapacitors and lithium-ion batteries / RSC Adv 9(17) : 9577~9583

[journal] Zhang H / 2020 / Nano-size porous carbon spheres as a high-capacity anode with high initial coulombic efficiency for potassium-ion batteries / Nanoscale Horiz 5(5) : 895~903

[journal] 김경수 / 2020 / The effect of waste PET addition on PFO-based anode materials for improving the electric capacity in lithium-ion battery / Carbon Letters / 한국탄소학회 30(5) : 545~553

[journal] 정희성 / 2021 / Oriented wrinkle textures of free-standing graphene nanosheets: application as a high-performance lithium-ion battery anode / Carbon Letters / 한국탄소학회 31(2) : 277~285

[journal] Liu B / 2008 / Metal-organic framework as a template for porous carbon synthesis / J Am Chem Soc 130(16) : 5390~5391

[journal] Zou G / 2016 / Cube-shaped porous carbon derived from MOF-5 as advanced material for sodium-ion batteries / Electrochim Acta 196 : 413~421

[journal] Li Y / 2018 / High pyridine N-doped porous carbon derived from metal–organic frameworks for boosting potassium-ion storage / J Mater Chem A 6(37) : 17959~17966

[journal] Peng HJ / 2017 / From metal-organic framework to porous carbon polyhedron : toward highly reversible lithium storage / Inorg Chem 56(16) : 10007~10012

[journal] Li X / 2018 / Metal-organic framework-derived carbons for battery applications / Adv Energy Mater 8(23) : 1800716~

[journal] Ganesan V / 2020 / Robust polyhedral CoTe2–C nanocomposites as high performance Li-and Na-ion battery anodes / ACS Appl Energy Mater 3(5) : 4877~4887

[journal] Xiong P / 2017 / Nitrogen–doped carbon nanotubes derived from metal–organic frameworks for potassium-ion battery anodes / Chemsuschem 11(1) : 202~208

[journal] Nam KH / 2021 / Superior carbon black : High-performance anode and conducting additive for rechargeable Li-and Na-ion batteries / Chem Eng J 417 : 129242~

[journal] Zhang F / 2009 / Hierarchical porous carbon derived from rice straw for lithium ion batteries with high-rate performance / Electrochem commun 11(1) : 130~133

[journal] Wang N / 2018 / N-doped catalytic graphitized hard carbon for high-performance lithium/sodium-ion batteries / Sci Rep 8 : 9934~

[journal] Chen T / 2014 / Electrospun carbon nanofibers as anode materials for sodium ion batteries with excellent cycle performance / J Mater Chem A 2(12) : 4117~4121

[journal] Zeng L / 2014 / N-doped porous hollow carbon nanofibers fabricated using electrospun polymer templates and their sodium storage properties / RSC Adv 4(33) : 16920~16927

[journal] Tai Z / 2017 / Activated carbon from the graphite with increased rate capability for the potassium ion battery / Carbon 123 : 54~61

[journal] Jian Z / 2015 / Carbon electrodes for K-ion batteries / J Am Chem Soc 137(36) : 11566~11569

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Porous polyhedral carbon matrix for high-performance Li/Na/K-ion battery anodes

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This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (2) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (4) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2025-01-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Porous polyhedral carbon matrix for high-performance Li/Na/K-ion battery anodes

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Scopus Citation Counts (4) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2025-01-01)

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