@article{ART003144580},
author={Zare Yasser and Munir Muhammad Tajammal and Rhee Kyong Yop and PARK SOOJIN},
title={Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={8},
pages={2149-2159},
doi={10.1007/s42823-024-00774-6}
TY - JOUR
AU - Zare Yasser
AU - Munir Muhammad Tajammal
AU - Rhee Kyong Yop
AU - PARK SOOJIN
TI - Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics
JO - Carbon Letters
PY - 2024
VL - 34
IS - 8
PB - Korean Carbon Society
SP - 2149
EP - 2159
SN - 1976-4251
AB - In this work, the depth of the interphase in graphene polymer systems is determined by the properties of graphene and interfacial parameters. Furthermore, the actual volume fraction and percolation onset of the nanosheets are characterized by the actual inverse aspect ratio, interphase depth, and tunneling distance. In addition, the dimensions of graphene, along with interfacial/interphase properties and tunneling characteristics, are utilized to develop the power-law equation for the conductivity of graphene-filled composites. Using the derived equations, the interphase depth, percolation onset, and nanocomposite conductivity are graphed against various ranges of the aforementioned factors. Moreover, numerous experimental data points for percolation onset and conductivity are presented to validate the equations. The optimal levels for interphase depth, percolation onset, and conductivity are achieved through high interfacial conductivity and large graphene nanosheets. In addition, increased nanocomposite conductivity can be attained with thinner nanosheets, a larger tunneling distance, and a thicker interphase. The calculations highlight the considerable impacts of interfacial/interphase factors and tunneling distance on the percolation onset. The highest nanocomposite conductivity of 0.008 S/m is acquired by the highest interfacial conduction of 900 S/m and graphene length (D) of 5 μm, while an insulated sample is observed at D < 1.2 μm. Therefore, higher interfacial conduction and larger nanosheets cause the higher nanocomposite conductivity, but the short nanosheets cannot promote the conductivity.
KW - Polymer graphene nanocomposites Conductivity Interphase deepness Interfacial features Percolation inception Tunneling effect
DO - 10.1007/s42823-024-00774-6
ER -
Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop and PARK SOOJIN. (2024). Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics. Carbon Letters, 34(8), 2149-2159.
Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop and PARK SOOJIN. 2024, "Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics", Carbon Letters, vol.34, no.8 pp.2149-2159. Available from: doi:10.1007/s42823-024-00774-6
Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop, PARK SOOJIN "Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics" Carbon Letters 34.8 pp.2149-2159 (2024) : 2149.
Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop, PARK SOOJIN. Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics. 2024; 34(8), 2149-2159. Available from: doi:10.1007/s42823-024-00774-6
Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop and PARK SOOJIN. "Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics" Carbon Letters 34, no.8 (2024) : 2149-2159.doi: 10.1007/s42823-024-00774-6
Zare Yasser; Munir Muhammad Tajammal; Rhee Kyong Yop; PARK SOOJIN. Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics. Carbon Letters, 34(8), 2149-2159. doi: 10.1007/s42823-024-00774-6
Zare Yasser; Munir Muhammad Tajammal; Rhee Kyong Yop; PARK SOOJIN. Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics. Carbon Letters. 2024; 34(8) 2149-2159. doi: 10.1007/s42823-024-00774-6
Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop, PARK SOOJIN. Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics. 2024; 34(8), 2149-2159. Available from: doi:10.1007/s42823-024-00774-6
Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop and PARK SOOJIN. "Advanced modeling of conductivity in graphene–polymer nanocomposites: insights into interface and tunneling characteristics" Carbon Letters 34, no.8 (2024) : 2149-2159.doi: 10.1007/s42823-024-00774-6
