@article{ART003144582},
author={He Yangdong and Wen Shaomu and Yang Wei and Qiao Changcang and Xie Ming and Chen Li and Yang Xinqi and Tang Yongliang},
title={Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={8},
pages={2161-2169},
doi={10.1007/s42823-024-00776-4}
TY - JOUR
AU - He Yangdong
AU - Wen Shaomu
AU - Yang Wei
AU - Qiao Changcang
AU - Xie Ming
AU - Chen Li
AU - Yang Xinqi
AU - Tang Yongliang
TI - Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column
JO - Carbon Letters
PY - 2024
VL - 34
IS - 8
PB - Korean Carbon Society
SP - 2161
EP - 2169
SN - 1976-4251
AB - The economical manufacturing of high-quality graphene has been a significant challenge in its large-scale application. Previously, we used molten Sn and Cu as the heat-transfer agent to produce multilayer graphene on the surface of gas bubbles in a bubble column. However, element Sn and Cu have poor catalytic activity toward methane pyrolysis. To further improve the yield of graphene, we have added active Ni into Sn to construct a Sn–Ni alloy in this work. The results show that Sn–Ni alloy is much more active for methane pyrolysis, and thus more graphene is obtained. However, the graphene product is more defective and thicker because of the faster growth rate. By using 300 ml molten Sn–Ni alloy (70 mm height) and 500 sccm source gas (CH4:Ar = 1:9), this approach produces graphene with a rate of 0.61 g/hr and a conversion rate of methane to carbon of 37.9% at 1250 ℃ and ambient pressure. The resulting graphene has an average atom layer number of 22, a crumpled structure and good electrical conductivity.
KW - Multilayer graphene Bubble column Molten Sn–Ni alloy Cost effective production
DO - 10.1007/s42823-024-00776-4
ER -
He Yangdong, Wen Shaomu, Yang Wei, Qiao Changcang, Xie Ming, Chen Li, Yang Xinqi and Tang Yongliang. (2024). Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column. Carbon Letters, 34(8), 2161-2169.
He Yangdong, Wen Shaomu, Yang Wei, Qiao Changcang, Xie Ming, Chen Li, Yang Xinqi and Tang Yongliang. 2024, "Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column", Carbon Letters, vol.34, no.8 pp.2161-2169. Available from: doi:10.1007/s42823-024-00776-4
He Yangdong, Wen Shaomu, Yang Wei, Qiao Changcang, Xie Ming, Chen Li, Yang Xinqi, Tang Yongliang "Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column" Carbon Letters 34.8 pp.2161-2169 (2024) : 2161.
He Yangdong, Wen Shaomu, Yang Wei, Qiao Changcang, Xie Ming, Chen Li, Yang Xinqi, Tang Yongliang. Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column. 2024; 34(8), 2161-2169. Available from: doi:10.1007/s42823-024-00776-4
He Yangdong, Wen Shaomu, Yang Wei, Qiao Changcang, Xie Ming, Chen Li, Yang Xinqi and Tang Yongliang. "Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column" Carbon Letters 34, no.8 (2024) : 2161-2169.doi: 10.1007/s42823-024-00776-4
He Yangdong; Wen Shaomu; Yang Wei; Qiao Changcang; Xie Ming; Chen Li; Yang Xinqi; Tang Yongliang. Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column. Carbon Letters, 34(8), 2161-2169. doi: 10.1007/s42823-024-00776-4
He Yangdong; Wen Shaomu; Yang Wei; Qiao Changcang; Xie Ming; Chen Li; Yang Xinqi; Tang Yongliang. Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column. Carbon Letters. 2024; 34(8) 2161-2169. doi: 10.1007/s42823-024-00776-4
He Yangdong, Wen Shaomu, Yang Wei, Qiao Changcang, Xie Ming, Chen Li, Yang Xinqi, Tang Yongliang. Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column. 2024; 34(8), 2161-2169. Available from: doi:10.1007/s42823-024-00776-4
He Yangdong, Wen Shaomu, Yang Wei, Qiao Changcang, Xie Ming, Chen Li, Yang Xinqi and Tang Yongliang. "Production of multilayer graphene using molten Sn–Ni alloy as catalyst in a bubble column" Carbon Letters 34, no.8 (2024) : 2161-2169.doi: 10.1007/s42823-024-00776-4
