@article{ART003144584},
author={Kim KyungSoo and Lee In Woo and Lee Yebin and Choi Yongcheol and Lee, Young-Seak},
title={Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={8},
pages={2171-2181},
doi={10.1007/s42823-024-00779-1}
TY - JOUR
AU - Kim KyungSoo
AU - Lee In Woo
AU - Lee Yebin
AU - Choi Yongcheol
AU - Lee, Young-Seak
TI - Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries
JO - Carbon Letters
PY - 2024
VL - 34
IS - 8
PB - Korean Carbon Society
SP - 2171
EP - 2181
SN - 1976-4251
AB - In this study, carbon coating was carried out by physical vapor deposition (PVD) on SiOx surfaces to investigate the effect of the deposited carbon layer on the performance of lithium-ion batteries as a function of the asphaltene content of petroleum residues. The petroleum residue was separated into asphaltene-free petroleum residue (ASF) and asphaltene-based petroleum residue (AS) containing 12.54% asphaltene by a solvent extraction method, and the components were analyzed. The deposited carbon coating layer became thinner, with the thickness decreasing from 15.4 to 8.1 nm, as the asphaltene content of the petroleum residue increased, and a highly crystalline layer was obtained. In particular, the SiOx electrode carbon-coated with AS exhibited excellent cycling performance with an initial efficiency of 85.5% and a capacity retention rate of 94.1% after 100 cycles at a current density of 1.0 C. This is because the carbon layer with enhanced crystallinity had sufficient thickness to alleviate the volume expansion of SiOx, resulting in stable SEI layer formation and enhanced structural stability. In addition, the SiOx electrode exhibited the lowest resistance with a low impedance of 23.35 Ω, attributed to the crystalline carbon layer that enhanced electrical conductivity and the mobility of Li ions. This study demonstrated that increasing the asphaltene content of petroleum residues is the simplest strategy for preparing SiOx@C anode materials with thin, crystalline carbon layers and excellent electrochemical performance with high efficiency and high rate performance.
KW - Lithium-ion batteries SiOx Carbon coating Petroleum residue Asphaltene
DO - 10.1007/s42823-024-00779-1
ER -
Kim KyungSoo, Lee In Woo, Lee Yebin, Choi Yongcheol and Lee, Young-Seak. (2024). Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries. Carbon Letters, 34(8), 2171-2181.
Kim KyungSoo, Lee In Woo, Lee Yebin, Choi Yongcheol and Lee, Young-Seak. 2024, "Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries", Carbon Letters, vol.34, no.8 pp.2171-2181. Available from: doi:10.1007/s42823-024-00779-1
Kim KyungSoo, Lee In Woo, Lee Yebin, Choi Yongcheol, Lee, Young-Seak "Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries" Carbon Letters 34.8 pp.2171-2181 (2024) : 2171.
Kim KyungSoo, Lee In Woo, Lee Yebin, Choi Yongcheol, Lee, Young-Seak. Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries. 2024; 34(8), 2171-2181. Available from: doi:10.1007/s42823-024-00779-1
Kim KyungSoo, Lee In Woo, Lee Yebin, Choi Yongcheol and Lee, Young-Seak. "Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries" Carbon Letters 34, no.8 (2024) : 2171-2181.doi: 10.1007/s42823-024-00779-1
Kim KyungSoo; Lee In Woo; Lee Yebin; Choi Yongcheol; Lee, Young-Seak. Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries. Carbon Letters, 34(8), 2171-2181. doi: 10.1007/s42823-024-00779-1
Kim KyungSoo; Lee In Woo; Lee Yebin; Choi Yongcheol; Lee, Young-Seak. Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries. Carbon Letters. 2024; 34(8) 2171-2181. doi: 10.1007/s42823-024-00779-1
Kim KyungSoo, Lee In Woo, Lee Yebin, Choi Yongcheol, Lee, Young-Seak. Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries. 2024; 34(8), 2171-2181. Available from: doi:10.1007/s42823-024-00779-1
Kim KyungSoo, Lee In Woo, Lee Yebin, Choi Yongcheol and Lee, Young-Seak. "Effect of asphaltene content in petroleum residues on carbon layer properties and the electrochemical performance of SiOx as an anode in lithium-ion batteries" Carbon Letters 34, no.8 (2024) : 2171-2181.doi: 10.1007/s42823-024-00779-1
