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Preparation and performance study of flexible all-solid-state Co9S8@P–C @ NiCo-LDH / / AC asymmetric supercapacitors

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2025, 35(1), pp.211~219
  • DOI : 10.1007/s42823-024-00784-4
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : May 5, 2024
  • Accepted : July 29, 2024
  • Published : March 28, 2025

HUI ZHANG 1

1Anhui University

Accredited

ABSTRACT

Supercapacitors, emerging as energy storage devices, face challenges in practical applications due to their relatively low energy density. In this study, we fabricate a novelty supercapacitor cathode composed of Co9S8, conductive phosphorus-doped carbon (P–C), and layered double hydroxides (LDH). The incorporation of a conductive layer significantly enhances charge transfer, capacity, and electrochemical stability, ultimately elevating the electrochemical performance of the cathode. The fabricated Co9S8@P–C@NiCo-LDH demonstrates an exceptional area-specific capacitance of 3.9 F cm−2 at a current density of 2 mA cm−2, along with remarkable cyclic stability, maintaining 98.9% of their capacity after 2000 cycles. The flexible asymmetric all-solid-state supercapacitor (AAS) assembled with Co9S8@P–C@NiCo-LDH and activated carbon (AC) exhibits a remarkable energy density of 0.065 mWh cm−2, corresponding to 325.0 W h kg−1. Moreover, it maintains excellent cycling stability even at elevated current densities of 10 mA cm−2. Following 5000 consecutive charge/discharge cycles, the AAS device maintains approximately 91.1% of its initial specific capacity. The AAS device successfully powered a 3V white LED for 5 min, further emphasizing its practicality.

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