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Sun-powered synthesis: harnessing multiwall carbon nanotube-EB photocatalytic magic in a unified photocatalytic-biocatalytic system for solar- driven L-glutamate production from ɑ-ketoglutarate

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2025, 35(1), pp.257~265
  • DOI : 10.1007/s42823-024-00780-8
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : February 13, 2024
  • Accepted : July 10, 2024
  • Published : March 28, 2025

Abhishek Mishra 1 Rajesh K. Yadav 1 Shaifali Mishra 1 Rehana Shahin 1 Satyam Singh 1 Abhishek Kumar Gupta 2 Rajat Singhal 3 Navneet K. Gupta 3 Jin‑OoK Baeg 4 Gamal A. El‑Hiti 5 Krishna Kumar Yadav 6 Sunita Singh 7

1Madan Mohan Malaviya University of Technology
2Harcourt Butler Technical University
3Indian Institute of Science, Bangalore Gulmohar Marg
4한국화학연구원
5King Saud University
6Madhyanchal Professional University
7University of Delhi

Accredited

ABSTRACT

Artificial photosynthesis, which mimics the natural process used by plants, offers a promising strategy for harnessing solar energy to produce valuable fuels. One intriguing approach is the photocatalyst-enzyme attached system, where a photocatalyst captures light energy and transfers it to an enzyme to drive specific chemical reactions. This study describes the synthesis of a novel photocatalyst (MWCNTCEBr) formed by coupling multiwall carbon nanotubes (MWCNTs) with a dye ethidium bromide (EBr) via a condensation reaction. The resulting photocatalyst exhibits excellent charge separation and migration abilities, leading to enhanced photocatalytic activity. Notably, MWCNTCEBr photocatalyst successfully converts α-Ketoglutarate to L-Glutamate (81.9%) and photo-regeneration of NADH (76.20%) under the influence of solar radiation. Therefore, the study demonstrates the development and the application of MWCNTCEBr photocatalyst for impressive NADH regeneration and bio-transformation.

Citation status

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Total Citation Counts(KCI+WOS) (2) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

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