본문 바로가기
  • Home

Enhanced selective Cu(II) detection using a high-performance EDTA/PVA/MWCNT-modified carbon paste electrode

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2025, 35(6), pp.2617~2632
  • DOI : 10.1007/s42823-025-00941-3
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : April 18, 2025
  • Accepted : June 16, 2025
  • Published : December 11, 2025

Perangin Angin Yurika Almanda 1 Wijaya Karna 1 Trisunaryanti Wega 1 Sari Reka Mustika 2 Destiarti Lia 3 Oh Won Chun ORD ID 4 Kim Sung Su 5 Ravindran Balasubramani 5 Chang Soon Woong 5 Ravi Karthikeyan 6

1Universitas Gadjah Mada
2Research Center for Food Technology and Processing, National Research and Innovation Agency
3Universitas Tanjungpura
4한서대학교
5경기대학교
6Chettinad Academy of Research and Education

Accredited

ABSTRACT

Water contamination caused by heavy metal pollutants from industrial activities remains a pressing environmental concern. This study reports the development of a novel carbon paste electrode (CPE) modified with ethylenediaminetetraacetic acid (EDTA), polyvinyl alcohol (PVA), and multi-walled carbon nanotubes (MWCNTs) using a mechanochemical method for the electrochemical detection of Cu(II) ions. The modified electrode was thoroughly characterized to evaluate its functional groups, morphology, crystallinity, elemental composition, and electrochemical properties. Electrochemical measurements were performed using cyclic voltammetry (CV) and square-wave anodic stripping voltammetry (SWASV) under optimized conditions in 0.1 M NH₄Cl at pH 5. The EDTA/PVA/MWCNT-CPE exhibited a low detection limit (0.0457 µM), a wide linear range (0.1–2.7 µM), and excellent reproducibility (RSD = 0.51%), repeatability (RSD = 0.43%), and stability (95% retention after six days). Selectivity tests demonstrated high recovery for Cu(II) (99.7%) and Hg(II) (99.89%) with minimal interference. This simple, cost-effective sensor offers high sensitivity and selectivity, making it a promising candidate for Cu(II) detection in environmental monitoring applications.

Citation status

* References for papers published after 2024 are currently being built.