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Facile synthesis of activated carbon/copper/copper oxide composite electrode material for supercapacitors using C.I. Pigment Blue 15:3

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2025, 35(6), pp.2717~2728
  • DOI : 10.1007/s42823-025-00949-9
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : May 29, 2025
  • Accepted : July 8, 2025
  • Published : December 11, 2025

Gunhwan Park 1 Woong Kwon 1 Jiyeon Cheon 1 Daeun Kim 1 Gyeongjin Kim 1 Euigyung Jeong ORD ID 1

1경북대학교

Accredited

ABSTRACT

In this study, C.I. Pigment Blue 15:3, an organic phthalocyanine based pigment, was used as a precursor to synthesize activated carbon/copper/copper oxide composite through a carbonization and activation process. The resulting composite was investigated to evaluate the potential use as a hybrid capacitor electrode of supercapacitor and pseudo-capacitor. Precursor was pre-treated at 600 °C, followed by activation at 750 °C using alkaline activating agents (KOH and K2CO3). Neutral ZnCl2 activating agent was also used for activation at 700 °C without pre-treatment to compare the electrochemical performance. The KOH activated sample exhibited the presence of Cu, CuO, and Cu2O in XRD and XPS analysis results and it also showed a highest specific surface area of 2731 m2/g and well-developed 0.7–2.0 nm micropores, enhancing ion adsorption in K2SO4 electrolyte. Electrochemical tests revealed that PB_KOH exhibited the highest capacitance, outperforming commercial Norit Carbon at various current densities, due to its Cu/CuO/Cu2O/activated carbon composite structure. These findings highlight its strong potential as a high-performance supercapacitor electrode material.

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This paper was written with support from the National Research Foundation of Korea.