@article{ART003274549},
author={Liu Hua and Wang Chenxin and Li Cheng and Yang Xuan and Li Cong and Song Zhi},
title={Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells},
journal={Carbon Letters},
issn={1976-4251},
year={2025},
volume={35},
number={6},
pages={2967-2979},
doi={10.1007/s42823-025-00969-5}
TY - JOUR
AU - Liu Hua
AU - Wang Chenxin
AU - Li Cheng
AU - Yang Xuan
AU - Li Cong
AU - Song Zhi
TI - Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells
JO - Carbon Letters
PY - 2025
VL - 35
IS - 6
PB - Korean Carbon Society
SP - 2967
EP - 2979
SN - 1976-4251
AB - The slow cathodic oxygen reduction rate (ORR) of microbial fuel cells (MFCs) is still one of the main bottlenecks in its industrialization. As an ORR catalyst, metal oxides are expected to significantly enhance ORR efficiency by providing active sites, regulating reaction pathways, and enhancing stability. In this paper, four bimetallic oxide catalysts, CuO/Co3O4, CuO/MnO2, CuO/NiO, and CuO/Fe2O3, were synthesized by sol–gel method, and their structural characteristics were characterized. The results showed that CuO/Co3O4 exhibited the largest specific surface area and optimized pore structure, and the synergistic effect of Cu and Co significantly improved the electrochemical performance. As the cathode catalyst of MFCs, CuO/Co3O4 shows high ORR catalytic activity, low charge transfer resistance, and good stability. In MFCs application, CuO/Co3O4 catalyst achieved the maximum power density of 227 mW m−2. In the five-cycle test, the output voltage is stable at about 240 mV, and the COD removal rate reaches 91.9%, which shows great application potential in wastewater treatment.
KW - Microbial fuel cell;Oxygen reduction reaction;Sol–gel method;Bimetallic oxide
DO - 10.1007/s42823-025-00969-5
ER -
Liu Hua, Wang Chenxin, Li Cheng, Yang Xuan, Li Cong and Song Zhi. (2025). Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells. Carbon Letters, 35(6), 2967-2979.
Liu Hua, Wang Chenxin, Li Cheng, Yang Xuan, Li Cong and Song Zhi. 2025, "Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells", Carbon Letters, vol.35, no.6 pp.2967-2979. Available from: doi:10.1007/s42823-025-00969-5
Liu Hua, Wang Chenxin, Li Cheng, Yang Xuan, Li Cong, Song Zhi "Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells" Carbon Letters 35.6 pp.2967-2979 (2025) : 2967.
Liu Hua, Wang Chenxin, Li Cheng, Yang Xuan, Li Cong, Song Zhi. Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells. 2025; 35(6), 2967-2979. Available from: doi:10.1007/s42823-025-00969-5
Liu Hua, Wang Chenxin, Li Cheng, Yang Xuan, Li Cong and Song Zhi. "Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells" Carbon Letters 35, no.6 (2025) : 2967-2979.doi: 10.1007/s42823-025-00969-5
Liu Hua; Wang Chenxin; Li Cheng; Yang Xuan; Li Cong; Song Zhi. Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells. Carbon Letters, 35(6), 2967-2979. doi: 10.1007/s42823-025-00969-5
Liu Hua; Wang Chenxin; Li Cheng; Yang Xuan; Li Cong; Song Zhi. Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells. Carbon Letters. 2025; 35(6) 2967-2979. doi: 10.1007/s42823-025-00969-5
Liu Hua, Wang Chenxin, Li Cheng, Yang Xuan, Li Cong, Song Zhi. Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells. 2025; 35(6), 2967-2979. Available from: doi:10.1007/s42823-025-00969-5
Liu Hua, Wang Chenxin, Li Cheng, Yang Xuan, Li Cong and Song Zhi. "Screening and optimization of Cu-based bimetallic oxide cathode catalysts and their study on the electricity generation effect in microbial fuel cells" Carbon Letters 35, no.6 (2025) : 2967-2979.doi: 10.1007/s42823-025-00969-5