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Growth and optical conductivity properties for MnAl2S4 single crystal thin film by hot wall epitaxy method

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2014, 24(6), pp.229-236
  • DOI : 10.6111/JKCGCT.2014.24.6.229
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering

You,Sang-Ha 1 이기정 1 Kwang Joon Hong 1 Moon,Jong-Dae 2

1조선대학교
2동신대학교

Accredited

ABSTRACT

A stoichiometric mixture of evaporating materials for MnAl2S4 single crystal thin films was prepared fromhorizontal electric furnace. To obtain the single crystal thin films, MnAl2S4 mixed crystal was deposited on thoroughlyetched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperatureswere 630oC and 410oC, respectively. The crystalline structure of the single crystal thin films was investigated by thephotoluminescence and double crystal X-ray diffraction (DCXD). The temperature dependence of the energy band gap ofthe MnAl2S4 obtained from the absorption spectra was well described by the Varshni's relation, Eg(T) = 3.7920 eV − (5.2729 ×10−4 eV/K)T2/(T + 786 K). In order to explore the applicability as a photoconductive cell, we measured the sensitivity (γ),the ratio of photocurrent to dark current (pc/dc), maximum allowable power dissipation (MAPD) and response time. Theresults indicated that the photoconductive characteristic were the best for the samples annealed in S vapour compare within Mn, Al, air and vacuum vapour. Then we obtained the sensitivity of 0.93, the value of pc/dc of 1.10 × 107, the MAPDof 316 mW, and the rise and decay time of 14.8 ms and 12.1 ms, respectively.

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