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Crystal growth of nanosized α-Fe2O3 particles in frit

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2018, 28(2), pp.69-73
  • DOI : 10.6111/JKCGCT.2018.28.2.069
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Published : April 30, 2018

Hiroaki-Katsuki 1 Choi Eun Kyoung 1 lee won jun 1 Won-Jin Moon 2 Ungsoo Kim 1 Kwangtaek Hwang 1 Wooseok Cho 1

1한국세라믹기술원
2한국기초과학지원연구원

Accredited

ABSTRACT

Crystal growth of α-Fe 2 O 3 nanosized particles of 80~90 nm in size, which were hydrothermally prepared from 0.03 M FeCl 3 solution at 100 o C, was investigated in Pb-containing and Pb-free frit. By heating α-Fe 2 O 3 nanosized particles in two frits at 800 o C, the average diameter of particles in frits was increased to 200~210 nm and 150~160 nm, respectively, and the crystal growth due to the aggregation and sintering of several α-Fe 2 O 3 particles was observed. Formation ratios of larger particles over 100 nm in diameter were 54 % in Pb-free frit and 85 % in Pb-containing frit. After heating α-Fe 2 O 3 particles in frits at 800 o C, 7~9 nm in average diameter of pores were formed in particles. Theses pores were derived from the porous structure of original α-Fe 2 O 3 particles and confined in particles during sintering.

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