A study on the synthesis of a cathode active material precursor from a waste lithium secondary battery (폐리튬이차전지 스크랩 재활용을 통한 양극활물질 전구체 합성 연구)

Boram Kim (김보람); Kim Dae Weon (김대원); Tae-heon Kim (김태헌); Jae-won Lee (이재원); Hang-Chul Jung (정항철); HAN DEOK HYUN (한덕현); Soo-Hoon Jung (정수훈); Dae-Hoon Yang (양대훈)

doi:10.6111/JKCGCT.2022.32.2.061

A study on the synthesis of a cathode active material precursor from a waste lithium secondary battery

Journal of the Korean Crystal Growth and Crystal Technology
Abbr : J. Korean Cryst. Growth Cryst. Technol.
2022, 32(2), pp.61-67
DOI : 10.6111/JKCGCT.2022.32.2.061
Publisher : The Korea Association Of Crystal Growth, Inc.
Research Area : Engineering > Materials Science and Engineering
Received : February 22, 2022
Accepted : March 11, 2022
Published : April 30, 2022

Boram Kim ¹, Kim Dae Weon ¹, Tae-heon Kim ², Jae-won Lee ², Hang-Chul Jung ¹, HAN DEOK HYUN ¹, Soo-Hoon Jung ³, Dae-Hoon Yang ³

¹고등기술연구원연구조합
²단국대학교
³(주)지엠텍

Accredited

ABSTRACT

A metal salt solution was prepared from valuable metals (Ni, Co, Mn) recovered from a scrap of waste lithium secondary batteries, and an NCM811 precursor was synthesized from the solution. The effect on precursor formation accordingto reaction time was confirmed by SEM, PSA, and ICP analysis. Based on the analysis results, the electrochemical properties of the synthesized NCM811 precursor and the commercial NCM811 precursor were investigated. The Galvano charge-discharge cycle, rate performance, and Cycle performance were compared, and as a result, there was no significant difference from commercial precursors.

KEYWORDS

Lithium secondary battery, Cathode active material, Precursor, NCM811, Taylor reaction

Citation status

* References for papers published after 2023 are currently being built.

[book] / 2020 / Lithium ion battery market-fore cast (2020-2025) / Markets and markets : 10~

[journal] 김수연 / 2017 / Synthesis and Electrochemical Performance of Ni-rich NCM Cathode Materials for Lithium-Ion Batteries / 전기화학회지 / 한국전기화학회 20(4) : 67~74

[journal] C.M. Julien / 2020 / NCA, NCM811, and the Route to Ni-Richer Lithium-Ion Batteries / Energies 13 : 6363~

[journal] M. Dixit / 2017 / Origin of structural degradation during cycling and low thermal stability of Ni-rich layered transition metal-based electrode materials / J. Phys. Chem. C 121 : 22628~

[journal] J.W. Lee / 2014 / Research trend of electrode materials for lithium rechargeable batteries / J. Powder Mater 21 : 473~

[book] J.H. Jo / 2017 / The analysis of secondary material flow and activation of resource circulation of rechargeable batteries / Korea Environment Institute : 74~

[journal] X. Hu / 2021 / Recovery of Co, Ni, Mn, and Li from Li-ion batteries by smelting reduction- Part I: A laboratory-scale study / J. Power Sources 483 : 228936~

[journal] W.Y. Wang / 2020 / High-performance recovery of Cobalt and Nickel from the cathode materials of NMC type Li-Ion Battery by complexationassisted solvent extraction / Minerals 10 : 662~

[journal] Y. Xin / 2016 / Bioleaching of valuable metals Li, Co, Ni and Mn from spent electric vehicle Li-ion batteries for the purpose of recovery / J. Clean. Prod 116 : 249~

[journal] C. Peng / 2019 / Elective extraction of lithium (Li) and preparation of battery grade lithium carbonate (Li2CO3) from spent Li-ion batteries in nitrate system / J. Power Sources 415 : 179~

[journal] 진연호 / 2021 / Correlation between Lithium Concentration and Ecotoxicoloigy in Lithium Contained Waste Water / Clean Technology / 한국청정기술학회 27(1) : 33~38

[journal] 김보람 / 2021 / A study on the fabrication of high purity lithium carbonate by recrystallization of low grade lithium carbonate / 한국결정성장학회지 / 한국결정성장학회 31(1) : 16~23

[journal] J. Wang / 2014 / Synthesis of calcium carbonate particles in octylamine/water bilayer systems / Kona 31 : 156~

[journal] D.K. Thai / 2015 / Agglomeration of Ni-rich hydroxide crystals in Taylor vortex flow / Powder Technol 274 : 5~

[journal] 권승예 / 2017 / Three-dimensional Fluid Flow Analysis in Taylor Reactor Using Computational Fluid Dynamics / 공업화학 / 한국공업화학회 28(4) : 448~453

[journal] 한덕현 / 2019 / Study on the Optimum Conditions for Synthesizing a Cathode Active Material Precursor in Li-Ion Batteries Using a Taylor Reactor / 대한금속·재료학회지 / 대한금속·재료학회 57(6) : 360~365

[journal] C.Y. Hu / 2011 / Effects of synthesis conditions on layered Li [Ni1/3Co1/3Mn1/3] O2 positive-electrode via hydroxide co-precipitation method for lithium-ion batteries / T. Nonferr. Metal. Soc. China 21 : 114~

[journal] Z.X. Tang / 1991 / Preparation of manganese ferrite fine particles from aqueous solution / J. Colloid Interface Sci 146 : 38~

[journal] C. G. Garay-Reyes / 2017 / Comparative Study of Oswald Ripening and Trans-Interface Diffusion-Controlled Theory Models: Coarsening of γ ' Precipitates Affected by Elastic Strain Along a Concentration Gradient / Metals and Materials International / 대한금속·재료학회 23(2) : 298~307

[journal] 박상혁 / 2015 / The Effect of NH3 Concentration during Co-precipitation of Precursors from Leachate of Lithium-ion Battery Positive Electrode Active Materials / 자원리싸이클링 / 한국자원리싸이클링학회 24(6) : 9~16

[journal] 박일정 / 2017 / A study on the synthesis of fine nickel hydroxide crystalline powder using the taylor fluid flow / 한국결정성장학회지 / 한국결정성장학회 27(5) : 268~273

KJCKorea
Journal Central

Journal of the Korean Crystal Growth and Crystal Technology 2023 KCI Impact Factor : 0.19

A study on the synthesis of a cathode active material precursor from a waste lithium secondary battery

ABSTRACT

KEYWORDS

Citation status

* References for papers published after 2023 are currently being built.

Journal of the Korean Crystal Growth and Crystal Technology 2023 KCI Impact Factor : 0.19

A study on the synthesis of a cathode active material precursor from a waste lithium secondary battery

ABSTRACT

KEYWORDS

Statistics

Tools

Issue List

Citation status

KCI Citation Counts (3)

REFERENCES (21) * References for papers published after 2023 are currently being built.

Search PDF

Citation

* References for papers published after 2023 are currently being built.