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Vanadium-doped semi-insulating SiC single crystal growth by using porous graphite

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2016, 26(6), pp.215-219
  • DOI : 10.6111/JKCGCT.2016.26.6.215
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : October 6, 2016
  • Accepted : November 4, 2016
  • Published : December 31, 2016

Dong-Hun Lee 1 Hwang-Ju Kim 1 Young-Gon Kim 1 Su-Hun Choi 1 Mi-Seon Park 1 Yeon-Suk Jang 1 Lee, Won Jae 1 Kwang-Hee Jung 2 Tae-Hee Kim 2 Yi-Sik Choi 2

1동의대학교
2사파이어테크놀로지

Accredited

ABSTRACT

Vanadium-doped SiC crystals have been grown by using a porous graphite inner crucible filled with vanadium carbide (VC) and by using a porous graphite plate and SiC + VC powders, respectively. Semi-insulating SiC crystals were grown onto the 6H-SiC seed crystals by PVT (Physical Vapor Transport) method. The grown crystals were indicated to be 6H-SiC polytype by XRD. As result of SIMS analysis, vanadium-rich precipitates were observed when the vanadium concentration was relatively higher than the maximum solubility of vanadium (3-5 × 10 17 cm−3 ) in vanadium-doped SiC crystals, which resulted in degradation of crystal quality.

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