@article{ART002177703},
author={Seungyun Han and Min-Chul Shin and Lee, Hee-Soo},
title={The deactivation behavior of SCR catalyst by alkali and alkali earth metal},
journal={Journal of the Korean Crystal Growth and Crystal Technology},
issn={1225-1429},
year={2016},
volume={26},
number={6},
pages={238-242},
doi={10.6111/JKCGCT.2016.26.6.238}
TY - JOUR
AU - Seungyun Han
AU - Min-Chul Shin
AU - Lee, Hee-Soo
TI - The deactivation behavior of SCR catalyst by alkali and alkali earth metal
JO - Journal of the Korean Crystal Growth and Crystal Technology
PY - 2016
VL - 26
IS - 6
PB - The Korea Association Of Crystal Growth, Inc.
SP - 238
EP - 242
SN - 1225-1429
AB - The effect of the alkali, alkali earth metal elements on selective catalytic reduction(SCR) catalyst deactivation behavior were investigated in terms of microstructure, surface area, pore volume and De-NOx test. Poisoned SCR catalyst were manufactured by injection of K2CO3, Na2CO3, Ca(CH3COO)2 · H2O, C4H6MgO4 · 4H2O, H3PO4 solutions in the new SCR catalyst at 350 o C for 6 hours. New and poisoned catalysts surface were similar. But specific surface area, pore volume decrease from Na, Mg, K, Ca, P compared to new SCR catalyst. Especially, Na poisoned catalyst surface area and pore size extremely decreased by 10.20 m 2 /g, 0.061 cm 2 /g. De-NOx test results of new and poisoned catalysts at 150~450 o C indicated that alkali metal (K, Na) poisoned SCR catalysts have the lowest De-NOx efficiency, alkali earth metal poisoned SCR catalysts (Ca, Mg) De-NOx efficiency are higher than alkali metal poisoned SCR catalysts. P poisoned SCR catalyst De-NOx efficiency is similar new SCR catalyst. It were considered that physical deactivation of SCR catalyst was affected by SCR catalyst surface area and pore volume change.
KW - SCR catalyst;Deactivation;Alkali metal;Phosphoric acid;Poisoning
DO - 10.6111/JKCGCT.2016.26.6.238
ER -
Seungyun Han, Min-Chul Shin and Lee, Hee-Soo. (2016). The deactivation behavior of SCR catalyst by alkali and alkali earth metal. Journal of the Korean Crystal Growth and Crystal Technology, 26(6), 238-242.
Seungyun Han, Min-Chul Shin and Lee, Hee-Soo. 2016, "The deactivation behavior of SCR catalyst by alkali and alkali earth metal", Journal of the Korean Crystal Growth and Crystal Technology, vol.26, no.6 pp.238-242. Available from: doi:10.6111/JKCGCT.2016.26.6.238
Seungyun Han, Min-Chul Shin, Lee, Hee-Soo "The deactivation behavior of SCR catalyst by alkali and alkali earth metal" Journal of the Korean Crystal Growth and Crystal Technology 26.6 pp.238-242 (2016) : 238.
Seungyun Han, Min-Chul Shin, Lee, Hee-Soo. The deactivation behavior of SCR catalyst by alkali and alkali earth metal. 2016; 26(6), 238-242. Available from: doi:10.6111/JKCGCT.2016.26.6.238
Seungyun Han, Min-Chul Shin and Lee, Hee-Soo. "The deactivation behavior of SCR catalyst by alkali and alkali earth metal" Journal of the Korean Crystal Growth and Crystal Technology 26, no.6 (2016) : 238-242.doi: 10.6111/JKCGCT.2016.26.6.238
Seungyun Han; Min-Chul Shin; Lee, Hee-Soo. The deactivation behavior of SCR catalyst by alkali and alkali earth metal. Journal of the Korean Crystal Growth and Crystal Technology, 26(6), 238-242. doi: 10.6111/JKCGCT.2016.26.6.238
Seungyun Han; Min-Chul Shin; Lee, Hee-Soo. The deactivation behavior of SCR catalyst by alkali and alkali earth metal. Journal of the Korean Crystal Growth and Crystal Technology. 2016; 26(6) 238-242. doi: 10.6111/JKCGCT.2016.26.6.238
Seungyun Han, Min-Chul Shin, Lee, Hee-Soo. The deactivation behavior of SCR catalyst by alkali and alkali earth metal. 2016; 26(6), 238-242. Available from: doi:10.6111/JKCGCT.2016.26.6.238
Seungyun Han, Min-Chul Shin and Lee, Hee-Soo. "The deactivation behavior of SCR catalyst by alkali and alkali earth metal" Journal of the Korean Crystal Growth and Crystal Technology 26, no.6 (2016) : 238-242.doi: 10.6111/JKCGCT.2016.26.6.238
