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TCC behavior of a shell phase in core/shell structure formed in Y-doped BaTiO3:an individual observation

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2020, 30(3), pp.110-116
  • DOI : 10.6111/JKCGCT.2020.30.3.110
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : May 14, 2020
  • Accepted : May 28, 2020
  • Published : June 30, 2020

Sang-Chae Jeon 1

1창원대학교

Accredited

ABSTRACT

Grains in the BaTiO3, which is used for a dielectric layer in MLCC(Multi-Layer Ceramic Capacitor) are necessary to form core/shell structure for a stable TCC(Temperature Coefficient of Capacitance) behavior. The shell property has been deduced from the whole TCC behavior of core/shell structure due to its tiny size, ~ few μm. This study demonstrates the individual TCC behavior of the shell phase measured by micro-contact measurement in a temperature range between 35 and 135°C. Pt electrode pairs deposited on an enlarged core/shell structure in a diffusion couple sample made the measurement possible. As a result, the DPT (Diffusion Phase Transition) behavior of the shell phase was revealed as a different TCC behavior from that of the core: a broad peak with Tm at 65°C. This would be also useful experimental data for a modelling that depicts dielectric-temperature behavior of core/shell structure.

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